FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2056960233> ?p ?o ?g. }

• W2056960233 endingPage "102" @default.
• W2056960233 startingPage "91" @default.
• W2056960233 abstract "This paper investigates heterogeneous water nucleation on ammonium ions in a supersonic jet using vibrational predissociation spectroscopy. For NH4+(H2O)n, it is revealed that nonhydrogen bonded NH stretching of NH4+ is resonant at 3300–3400 cm−1, which is fairly independent of the cluster size of n = 2–4. The frequencies, however, shift strongly from ∼2900 cm−1 of n = 2 to ∼3100 cm−1 of n = 4 for hydrogen bonded NH stretches. Hydration at the second shell starting with n = 5 has little effect on the ion core vibrations. Similar to the NH oscillations, nonhydrogen bonded and hydrogen bonded OH stretches are found for the solvent molecules at 3600–3800 and 3300–3600 cm−1, respectively. Simultaneous observations of these four distinct stretches allow us to identify a number of structural isomers (both cyclic and noncyclic) at n = 4–6. Of particular interest is that the clusters form an energetically favored four-membered ring at n = 5 that is evidenced by its characteristic bonded OH stretching absorptions at ∼3550 cm−1. This ring shaped structure remains at n ≥ 5, where a sharp feature that can be ascribed to the nonhydrogen bonded OH stretching of three-coordinated H2O emerges at ∼3690 cm−1. All the results, both frequencies and assignments, are in close agreement with recent ab initio calculations. The association of the present observations with heterogeneous water nucleation in the gas phase and the infrared spectroscopy of neutral water clusters and crystalline ice is discussed." @default.
• W2056960233 created "2016-06-24" @default.
• W2056960233 creator A5006792025 @default.
• W2056960233 creator A5035084130 @default.
• W2056960233 creator A5075898848 @default.
• W2056960233 creator A5089443280 @default.
• W2056960233 date "1998-11-01" @default.
• W2056960233 modified "2023-10-16" @default.
• W2056960233 title "Studying protonated ion hydration by infrared spectroscopy of size-selected NH4+(H2O)n clusters in a free jet expansion" @default.
• W2056960233 cites W1964043485 @default.
• W2056960233 cites W1964255231 @default.
• W2056960233 cites W1964572546 @default.
• W2056960233 cites W1964826698 @default.
• W2056960233 cites W1969928621 @default.
• W2056960233 cites W1976967728 @default.
• W2056960233 cites W1979980334 @default.
• W2056960233 cites W1979981974 @default.
• W2056960233 cites W1985765590 @default.
• W2056960233 cites W1990428012 @default.
• W2056960233 cites W1991452898 @default.
• W2056960233 cites W2000827899 @default.
• W2056960233 cites W2001740136 @default.
• W2056960233 cites W2016115283 @default.
• W2056960233 cites W2017385820 @default.
• W2056960233 cites W2021758551 @default.
• W2056960233 cites W2032469534 @default.
• W2056960233 cites W2033181175 @default.
• W2056960233 cites W2033869281 @default.
• W2056960233 cites W2036117599 @default.
• W2056960233 cites W2038128301 @default.
• W2056960233 cites W2045177722 @default.
• W2056960233 cites W2051802559 @default.
• W2056960233 cites W2059281420 @default.
• W2056960233 cites W2063620051 @default.
• W2056960233 cites W2070011765 @default.
• W2056960233 cites W2071342308 @default.
• W2056960233 cites W2077496695 @default.
• W2056960233 cites W2080030733 @default.
• W2056960233 cites W2082131441 @default.
• W2056960233 cites W2082913410 @default.
• W2056960233 cites W2090470824 @default.
• W2056960233 cites W2158435561 @default.
• W2056960233 cites W2771905434 @default.
• W2056960233 cites W2952262185 @default.
• W2056960233 cites W3034078368 @default.
• W2056960233 cites W325017935 @default.
• W2056960233 doi "https://doi.org/10.1016/s1387-3806(98)14065-4" @default.
• W2056960233 hasPublicationYear "1998" @default.
• W2056960233 type Work @default.
• W2056960233 sameAs 2056960233 @default.
• W2056960233 citedByCount "46" @default.
• W2056960233 countsByYear W20569602332012 @default.
• W2056960233 countsByYear W20569602332013 @default.
• W2056960233 countsByYear W20569602332014 @default.
• W2056960233 countsByYear W20569602332015 @default.
• W2056960233 countsByYear W20569602332020 @default.
• W2056960233 countsByYear W20569602332021 @default.
• W2056960233 countsByYear W20569602332022 @default.
• W2056960233 crossrefType "journal-article" @default.
• W2056960233 hasAuthorship W2056960233A5006792025 @default.
• W2056960233 hasAuthorship W2056960233A5035084130 @default.
• W2056960233 hasAuthorship W2056960233A5075898848 @default.
• W2056960233 hasAuthorship W2056960233A5089443280 @default.
• W2056960233 hasConcept C112887158 @default.
• W2056960233 hasConcept C113196181 @default.
• W2056960233 hasConcept C120665830 @default.
• W2056960233 hasConcept C121332964 @default.
• W2056960233 hasConcept C145148216 @default.
• W2056960233 hasConcept C153642686 @default.
• W2056960233 hasConcept C158355884 @default.
• W2056960233 hasConcept C164866538 @default.
• W2056960233 hasConcept C178790620 @default.
• W2056960233 hasConcept C183971685 @default.
• W2056960233 hasConcept C185592680 @default.
• W2056960233 hasConcept C199360897 @default.
• W2056960233 hasConcept C2775902025 @default.
• W2056960233 hasConcept C2780378348 @default.
• W2056960233 hasConcept C30095370 @default.
• W2056960233 hasConcept C32891209 @default.
• W2056960233 hasConcept C32909587 @default.
• W2056960233 hasConcept C41008148 @default.
• W2056960233 hasConcept C61048295 @default.
• W2056960233 hasConcept C62520636 @default.
• W2056960233 hasConcept C8010536 @default.
• W2056960233 hasConceptScore W2056960233C112887158 @default.
• W2056960233 hasConceptScore W2056960233C113196181 @default.
• W2056960233 hasConceptScore W2056960233C120665830 @default.
• W2056960233 hasConceptScore W2056960233C121332964 @default.
• W2056960233 hasConceptScore W2056960233C145148216 @default.
• W2056960233 hasConceptScore W2056960233C153642686 @default.
• W2056960233 hasConceptScore W2056960233C158355884 @default.
• W2056960233 hasConceptScore W2056960233C164866538 @default.
• W2056960233 hasConceptScore W2056960233C178790620 @default.
• W2056960233 hasConceptScore W2056960233C183971685 @default.
• W2056960233 hasConceptScore W2056960233C185592680 @default.
• W2056960233 hasConceptScore W2056960233C199360897 @default.
• W2056960233 hasConceptScore W2056960233C2775902025 @default.
• W2056960233 hasConceptScore W2056960233C2780378348 @default.

• next