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• W2325021191 abstract "The reaction of H atoms with TiCl4 was studied behind reflected shock waves at temperatures between 1190 and 1500 K and pressures around 1.5 bar by applying atomic resonance absorption spectrometry for time-resolved measurements of H atoms at the Lα line. The thermal decomposition of ethyl iodide (C2H5I) served as the H atom source. By using a high excess of TiCl4, the consumption of H could be modeled by pseudo first-order kinetics. For the reaction TiCl4 + H → TiCl3 + HCl a temperature-independent rate coefficient of k1 = 3.5 ± 0.9 × 1013 cm3 mol-1 s-1 was found for the temperature range of the present experiments." @default.
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• W2325021191 date "1997-12-01" @default.
• W2325021191 modified "2023-09-24" @default.
• W2325021191 title "Shock Tube Study of the Reaction of H Atoms with TiCl₄" @default.
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• W2325021191 doi "https://doi.org/10.1021/jp9718414" @default.
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