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• W2790033667 abstract "Abstract Bimetallic chromium catalysts are investigated for the enantioselective polymerization of propylene oxide. The catalyst is composed of two salen chromium species linked by an alkyl chain, the length of which significantly impacts the rate of polymerization. While the use of a chloride initiator on the catalyst resulted in bimodal molecular weight distributions, switching to a trifluoroacetate initiating group and adding a diol chain transfer agent afforded polymers of controllable molecular weight with low, unimodal dispersities." @default.
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• W2790033667 date "2018-04-25" @default.
• W2790033667 modified "2023-10-10" @default.
• W2790033667 title "Bimetallic Chromium Catalysts with Chain Transfer Agents: A Route to Isotactic Poly(propylene oxide)s with Narrow Dispersities" @default.
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• W2790033667 doi "https://doi.org/10.1002/anie.201801380" @default.
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