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• W4226509701 endingPage "2200451" @default.
• W4226509701 startingPage "2200451" @default.
• W4226509701 abstract "Hydrogen-bonded organic framework-based host–guest ultralong organic phosphorescence (HOF-based HGUOP) materials with phosphorescent thermochromism property will become the next generation of intelligent optical functional materials in the future. Herein, three base-tuning HOF-based HGUOP co-crystal materials, Ma&Ct, Ma&Ae and Ma&Tm, are firstly created by respectively doping 1 mol% cytosine (Ct), adenine (Ae) and thymine (Tm) into melamine (Ma) host, these guests respectively lead to the blue shift, red shift and quenching of phosphorescence for Ma host. Notably, Ma&Ct performs an intensive “1 + 1 > 2” sensitized effect for photoluminescence (PL) and phosphorescence based on various synergetic interactions, the PL and phosphorescence quantum yields respectively get to 94.55 and 37.11%. The concentration and temperature-dependent photophysical performances of Ma&Ct, Ma&Ae and Ma&Tm are also recorded and analyzed. Relative mechanisms of phosphorescent thermochromism are firstly investigated deeply for Ma&Ct, Ma&Ae and Ma&Tm. In addition, phosphorescent thermochromism property of Ma&Ct and Ma&Ae have been well employed for information security and phosphorescent thermometer applications. This work not only proposes a simple preparation method of these new-type base-tuning HOF-based HGUOP co-crystal materials, but also explores the new internal phosphorescent thermochromism mechanism of these HOF-based HGUOP materials, which provides a typical case of HOF-based HGUOP materials using as smart flexible wearable phosphorescent thermometer." @default.
• W4226509701 created "2022-05-05" @default.
• W4226509701 creator A5026996885 @default.
• W4226509701 creator A5079294349 @default.
• W4226509701 date "2022-04-06" @default.
• W4226509701 modified "2023-10-14" @default.
• W4226509701 title "Base‐Tuning HOF‐Based Host–Guest Ultralong Organic Phosphorescence Systems with Phosphorescent Thermochromism Using for Information Security and Thermometer" @default.
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• W4226509701 doi "https://doi.org/10.1002/adom.202200451" @default.
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