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- W1199471805 abstract "Novel partially bio-based polyimides were prepared from 2, 5-diamino-2, 5-dideoxy-1, 4: 3, 6-dianhydrosorbitol (diaminoisosorbide, DAIS) dihydrochloride, 2, 5-diamino-2, 5-dideoxy-1, 4: 3, 6-dianhydroiditol (diaminoisoidide, DAII) dihydrochloride, and various dianhydrides via a conventional one-step method in m-cresol. Inherent viscosity values of these polyimides spanned a range of 0.5–1.5 dL/g. Flexible and transparent films can be easily cast from their corresponding solutions. The chemical structures and properties of isohexide-derived polyimides were fully characterized by using a variety of analytical techniques. The results revealed that the thermal and mechanical properties of isohexide-derived polyimides were similar to those derived from petrochemical-based diamines. Moreover, these polyimides exhibited good optical transparency, and optical activity. The good overall properties of isohexide-derived polyimides can be contributed to the incorporation of unique isohexide moieties that were rigid, thermally stable, fully aliphatic and chiral." @default.
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- W1199471805 date "2015-09-01" @default.
- W1199471805 modified "2023-10-14" @default.
- W1199471805 title "Partially bio-based polyimides from isohexide-derived diamines" @default.
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- W1199471805 doi "https://doi.org/10.1016/j.polymer.2015.07.051" @default.
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