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- W1550151487 abstract "In recent years novel ceramic fibers of nominal SiBN3C composition have been synthesized via pyrolysis of a preceramic polyborosilazane employing a single source Cl3Si-NH-BCl2 (TADB) precursor. The polymer can be transformed to a green fiber via melt-spinning followed by an intermediate curing step and successive pyrolysis. Despite their amorphous nature in the as-processed condition these fibers have demonstrated excellent high-temperature stability and are less prone to time-dependent failure as compared to conventional SiC-based fibers [1,2]. On a nanometer scale SiBNsC fibers undergo characteristic microstructural changes upon annealing in oxidizing and reducing atmospheres respectively which have been studied through the combined approach of high-resolution and analytical (x-ray microanalysis (EDS), energy loss spectroscopy (EELS), energy-filtered imaging (EFI)) transmission electron microscopy. From this research two typical SiBN3C microstructures will be presented in this brief outline." @default.
- W1550151487 created "2016-06-24" @default.
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- W1550151487 date "2001-10-12" @default.
- W1550151487 modified "2023-09-26" @default.
- W1550151487 title "Microstructural Response of SiBN <sub>3</sub> C‐Fibers Upon Annealing in Oxidizing and Reducing Atmospheres" @default.
- W1550151487 doi "https://doi.org/10.1002/3527605622.ch17" @default.
- W1550151487 hasPublicationYear "2001" @default.
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