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• W1963561866 abstract "The pyrolysis of methanol in shock waves at 1800–2740 K is studied by laser schlieren densitometry and dynamic mass spectrometry. A mechanism based on literature data and the present experiments is proposed and used to interpret the results by detailed computer simulation. A set of seven rate constants to which the data are most sensitive is identified. The values of these rate constants are adjusted to fit the data, using a systematic procedure depending upon sensitivity analysis and the extimated accuracy of the literature values of the rate constants in the mechanism. For the initiation process at 1900–2700 K we find k=9.7 × 1045 T−8.0exp(−376.6 kJ mol−RT) cm3 mol− s−1, which is the sum of the rate constants for the two channels CH3OH + M → CH3 + OH + M, (1) CH3OH + M → CH2OH + H + M. (1a) The ratio of these two rates is identified. Adjusted values of the rate constants for the following reactions are also suggested: CH3OH + H → CH2OH + H2, (5) CH2OH + M → CH2O + H + M, (9) CH2O + H → CHO + H2, (27) CHO + M → CO + H + M, (31) CHO + H → CO + H2, (32) CH2OH + H → CH2O + H2. (90)" @default.
• W1963561866 created "2016-06-24" @default.
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• W1963561866 date "1992-02-01" @default.
• W1963561866 modified "2023-10-07" @default.
• W1963561866 title "A kinetic study of the pyrolysis of methanol using shock tube and computer simulation techniques" @default.
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• W1963561866 doi "https://doi.org/10.1016/0010-2180(92)90050-y" @default.
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