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- W1963911330 abstract "The mechanism of base catalyzed proton exchange at the 5-position of uracil and its N-methylated derivatives has been studied. These reactions proceed by addition — elimination across the 5,6-double bond when the 1-nitrogen is substituted with a methyl group, or with anchimeric assistance of the N-1 anion if the 1-position is unsubstituted. The base catalyzed hydrolyses of 1,3-dimethyluracil and 3-methyluracil also appear to proceed through hydrated intermediates. A facile method for an acid catalyzed preparation of 5-deuterated uracils is described as well as a simple and accurate method for analysis of deuterium content." @default.
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- W1963911330 date "1970-08-01" @default.
- W1963911330 modified "2023-09-27" @default.
- W1963911330 title "Studies on the preparation and exchange reactions of 5-deuterated uracils" @default.
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- W1963911330 doi "https://doi.org/10.1002/jhet.5570070425" @default.
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