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- W1970101402 abstract "Abstract A new synthetic approach to (S)-coriolic acid 1 has been developed, starting from the readily available (E)-1-bromo-2-trimethylsilylethene 4 and trimethylsilylacetylene 5. A simple acylation reaction of 4, followed by a coupling reaction of the halogenoderivative intermediate with 5 in the presence of a Pd(0) catalyst affords the monosilylated ketoenyne 7. After desilylation of 7, enantioselective reduction of the carbonyl group with (S)-BINAL-H leads to the alcohol 2 (e.e.=94%). A subsequent coupling reaction and stereoselective reduction of the triple bond affords the target molecule 1." @default.
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- W1970101402 date "2010-06-09" @default.
- W1970101402 modified "2023-09-25" @default.
- W1970101402 title "ChemInform Abstract: Novel Synthetic Approach to (S)-Coriolic Acid." @default.
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- W1970101402 doi "https://doi.org/10.1002/chin.200015205" @default.
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