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- W1972063186 abstract "A series of manganese(II) complexes [{Mn(EC6H2R′3-2,4,6)2}](E = Se, R′= Me or But., E = Te, R′= Me) have been prepared by protolysis of [Mn{N(SiMe3)2}2(thf)](thf = tetrahydrofuran) with the corresponding sterically demanding arenechalcogenols 2,4,6-R′3C6H2EH. Complexes with R′= Me form co-ordination polymers which are soluble only in strongly co-ordinating solvents, while complexes with R′= But are dimeric and readily dissolve in less polar solvents such as toluene. The complexes react with Lewis bases (PMe3,2,2′-bipyridyl) to form tetrahedral or octahedral adducts, depending on the steric requirements of the arenechalcogenolate ligands. The structure of [{Mn(µ-SeC6H2Me3-2,4,6)2}∞] was determined by X-ray diffraction. The compound forms a one-dimensional infinite chain with bridging selenolate ligands which surround the metal centre in a flattened tetrahedral geometry." @default.
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- W1972063186 date "1995-01-01" @default.
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- W1972063186 title "Synthesis and characterisation of manganese(<scp>II</scp>) chalcogenolato complexes. Crystal and molecular structure of [{Mn(µ-SeC<sub>6</sub>H<sub>2</sub>Me<sub>3</sub>-2,4,6)<sub>2</sub>}<sub>∞</sub>]" @default.
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- W1972063186 doi "https://doi.org/10.1039/dt9950001645" @default.
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