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- W1973304686 abstract "Thermal reactions of some cis- and trans-[Coen2(OCOC6H4X)2]NO3 complexes mixed with ammonium or sodium chloride, nitrate and sulphate are reported. Reflectance spectra have shown a cis to trans thermal isomerization and, in the presence of NH4Cl, the formation of trans-[Coen2Cl2]Y as final product. For the cis-isomers, the most interesting result is the chromatographic evidence of a stepwise reaction, resulting in the replacement of one carboxylato ligand by chloride and the formation of an intermediate species, characterized as trans-[Coen2(OCOC6H4X)Cl]Y. These intermediate species, are hardly detectable in the corresponding reactions of the trans-isomers. These results may mean that in the trans-carboxylato compounds the reaction rate of the second step is higher than that of the first, while the reverse can be supposed in the corresponding reaction of the cis-isomers." @default.
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- W1973304686 date "1977-04-01" @default.
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- W1973304686 title "Chromatographic study of thermal reactions of cis- and trans-[Coen2 (OCOC6H4X)2]NO3 complexes in the solid phase" @default.
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- W1973304686 doi "https://doi.org/10.1016/0040-6031(77)80050-6" @default.
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