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- W1974382012 abstract "A new series of lanthanide-containing dicyanoaurate coordination polymers, [nBu4N]2[Ln(NO3)4Au(CN)2] (Ln = Nd, Eu, Gd or Tb), were synthesized and structurally characterized. They form an isomorphous series, crystallizing in the space group I212121. The structure is composed of a one dimensional zigzag of Ln–N–C–Au–C–N–Ln chains with no intra- or inter-chain aurophilic interactions. The series is related to and can be described as a reduced dimensionality analogue of the previously studied Ln[Au(CN)2]3·3H2O. Unlike the Ln[Au(CN)2]3·3H2O series, there is no efficient energy transfer between dicyanoaurate and the lanthanide metal centers in the complexes and they essentially act as two separate emissive chromophores." @default.
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- W1974382012 date "2012-01-01" @default.
- W1974382012 modified "2023-10-16" @default.
- W1974382012 title "Heterobimetallic lanthanide–gold coordination polymers: structure and emissive properties of isomorphous [nBu4N]2[Ln(NO3)4Au(CN)2] 1-D chains" @default.
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- W1974382012 doi "https://doi.org/10.1039/c2dt30156c" @default.
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