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- W1977563992 abstract "NMR titration curves have been recorded for all the 13C resonances of cis and transN-acetyl-dl-proline in 2H2O. the measured pK2H values are 3.4 ± 0.8 and 4.13 ± 0.08 respectively; the free energy of ionization for the trans isomer being (3.8 kJ/mole) greater than for the cis. The ionization shifts of the two isomers differ significantly only at the acetyl carbonyl and Cγ positions. It is suggested that these are related to conformational changes which stabilize the trans form at low p2H." @default.
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- W1977563992 date "1974-05-01" @default.
- W1977563992 modified "2023-10-16" @default.
- W1977563992 title "13C magnetic resonance study of the ionization of N-acetyl-dl-proline in aqueous solution" @default.
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- W1977563992 doi "https://doi.org/10.1016/0304-4165(74)90286-4" @default.
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