Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978775475> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W1978775475 endingPage "7280" @default.
- W1978775475 startingPage "7276" @default.
- W1978775475 abstract "The synthesis of poly(trifluoropropylmethyl)siloxane (PTFPMS) by anionic ring-opening polymerization of 1,3,5-tris(trifluoropropylmethyl)cyclotrisiloxane (F3) was studied in miniemulsion using didodecyldimethylammonium bromide (DDDBr) as emulsifier and sodium hydroxide as initiator. This new process of polymerization produced well-defined α,ω-dihydroxylated polymer in very high yields and with molar masses ranging from 2000 to 30 000 g mol-1. A kinetic study showed that polymerization occurs in two stages. During the first stage, which corresponds to the anionic kinetically controlled ring-opening polymerization of F3, the maximum nonequilibrium yield is close to 100%. The second stage involves condensation and backbiting reactions. The delay between these steps offers a broad “termination window” for achieving high polymer yield." @default.
- W1978775475 created "2016-06-24" @default.
- W1978775475 creator A5012569591 @default.
- W1978775475 creator A5025450390 @default.
- W1978775475 creator A5054425081 @default.
- W1978775475 creator A5088131465 @default.
- W1978775475 date "2001-09-12" @default.
- W1978775475 modified "2023-10-18" @default.
- W1978775475 title "Anionic Polymerization of 1,3,5-Tris(trifluoropropylmethyl)cyclotrisiloxane (F<sub>3</sub>) in Miniemulsion" @default.
- W1978775475 cites W2013098340 @default.
- W1978775475 cites W2025708143 @default.
- W1978775475 cites W2040839478 @default.
- W1978775475 cites W2091597454 @default.
- W1978775475 cites W2093006522 @default.
- W1978775475 cites W2124701852 @default.
- W1978775475 cites W2152366069 @default.
- W1978775475 cites W4255748564 @default.
- W1978775475 doi "https://doi.org/10.1021/ma010559z" @default.
- W1978775475 hasPublicationYear "2001" @default.
- W1978775475 type Work @default.
- W1978775475 sameAs 1978775475 @default.
- W1978775475 citedByCount "64" @default.
- W1978775475 countsByYear W19787754752012 @default.
- W1978775475 countsByYear W19787754752013 @default.
- W1978775475 countsByYear W19787754752014 @default.
- W1978775475 countsByYear W19787754752015 @default.
- W1978775475 countsByYear W19787754752016 @default.
- W1978775475 countsByYear W19787754752017 @default.
- W1978775475 countsByYear W19787754752018 @default.
- W1978775475 countsByYear W19787754752019 @default.
- W1978775475 countsByYear W19787754752020 @default.
- W1978775475 countsByYear W19787754752021 @default.
- W1978775475 countsByYear W19787754752022 @default.
- W1978775475 crossrefType "journal-article" @default.
- W1978775475 hasAuthorship W1978775475A5012569591 @default.
- W1978775475 hasAuthorship W1978775475A5025450390 @default.
- W1978775475 hasAuthorship W1978775475A5054425081 @default.
- W1978775475 hasAuthorship W1978775475A5088131465 @default.
- W1978775475 hasConcept C126348684 @default.
- W1978775475 hasConcept C178790620 @default.
- W1978775475 hasConcept C185592680 @default.
- W1978775475 hasConcept C188027245 @default.
- W1978775475 hasConcept C2776024560 @default.
- W1978775475 hasConcept C2781014771 @default.
- W1978775475 hasConcept C44228677 @default.
- W1978775475 hasConcept C521977710 @default.
- W1978775475 hasConcept C55493867 @default.
- W1978775475 hasConceptScore W1978775475C126348684 @default.
- W1978775475 hasConceptScore W1978775475C178790620 @default.
- W1978775475 hasConceptScore W1978775475C185592680 @default.
- W1978775475 hasConceptScore W1978775475C188027245 @default.
- W1978775475 hasConceptScore W1978775475C2776024560 @default.
- W1978775475 hasConceptScore W1978775475C2781014771 @default.
- W1978775475 hasConceptScore W1978775475C44228677 @default.
- W1978775475 hasConceptScore W1978775475C521977710 @default.
- W1978775475 hasConceptScore W1978775475C55493867 @default.
- W1978775475 hasIssue "21" @default.
- W1978775475 hasLocation W19787754751 @default.
- W1978775475 hasOpenAccess W1978775475 @default.
- W1978775475 hasPrimaryLocation W19787754751 @default.
- W1978775475 hasRelatedWork W1965673560 @default.
- W1978775475 hasRelatedWork W1984298436 @default.
- W1978775475 hasRelatedWork W1989790225 @default.
- W1978775475 hasRelatedWork W1997722815 @default.
- W1978775475 hasRelatedWork W2005573252 @default.
- W1978775475 hasRelatedWork W2006914890 @default.
- W1978775475 hasRelatedWork W2007365510 @default.
- W1978775475 hasRelatedWork W2288253545 @default.
- W1978775475 hasRelatedWork W2325821681 @default.
- W1978775475 hasRelatedWork W2347691272 @default.
- W1978775475 hasVolume "34" @default.
- W1978775475 isParatext "false" @default.
- W1978775475 isRetracted "false" @default.
- W1978775475 magId "1978775475" @default.
- W1978775475 workType "article" @default.