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- W1984459218 abstract "The reactions of 4-nitrobenzenesulfenyl chloride with substituted benzylamines proceed through three pathways, the uncatalyzed (<TEX>$k_2$</TEX>) and catalyzed (<TEX>$k_3$</TEX>) paths including solvolysis (<TEX>$k_o$</TEX>) by the solvent. The large value of primary normal kinetic isotope effects imply that the proton transfer occurs concurrently from benzylamine to Cl atom of the substrate. The <TEX>${beta}_x$</TEX> and <TEX>${rho}_x$</TEX> values for the catalyzed path, <TEX>$k_3$</TEX>, are greater than those for the uncatalyzed path, indicating that greater degree of bond formation in the catalyzed TS compared to the uncatalyzed TS." @default.
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- W1984459218 date "2011-03-20" @default.
- W1984459218 modified "2023-10-16" @default.
- W1984459218 title "Aminolysis of 4-Nitrobenzenesulfenyl Chloride" @default.
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- W1984459218 doi "https://doi.org/10.5012/bkcs.2011.32.3.1071" @default.
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