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- W1986357588 abstract "A highly stereoselective synthesis of the Aspidosperma ring system is described, based on a combination of two stereocontrolled processes. The first features a base-catalyzed cyclization of the imine 5 to generate the indoline 4. The second involves the formation of tetracycle 2 by the ring closure of N-acyliminium ion 3, whereby an allylsilane moiety functions as π-nucleophile." @default.
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- W1986357588 date "1990-01-01" @default.
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- W1986357588 title "Synthesis of the aspidosperma skeleton through allylsilane N-acyliminium cyclization" @default.
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- W1986357588 doi "https://doi.org/10.1016/s0040-4020(01)90540-x" @default.
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