Matches in SemOpenAlex for { <https://semopenalex.org/work/W1992322354> ?p ?o ?g. }
- W1992322354 endingPage "2113" @default.
- W1992322354 startingPage "2104" @default.
- W1992322354 abstract "A preorganized cationic receptor 2 for cytosine (C) is described which is composed of trans-a2PtII (a= NH3 or CH3NH2) cross-linked modules with adenine (A), guanine (G), and uracil (U) or thymine (T) model nucleobases. The functions of these three modules are as follows: i) Adenine orientates the two other bases at right angles, thus producing the L-shape of the receptor. ii) Guanine is the primary receptor. iii) Uracil or thymine act as coreceptors. Compared with the normal Watson-Crick pair between G and C, the association constant between 2 and C increases by a factor of 3 (in DMSO). As deduced from 1H NMR spectroscopy and confirmed by the X-ray crystal structure of the C adduct 4b, cytosine is fixed through five hydrogen bonds to the receptor, one of which involves the aromatic H(5) of C. A comparison of C binding is made with a structurally related linkage isomer receptor as well as the precursor molecule trans[alpha2PtAG]2+. The potential of modular, cationic receptors is illustrated." @default.
- W1992322354 created "2016-06-24" @default.
- W1992322354 creator A5027148319 @default.
- W1992322354 creator A5043059401 @default.
- W1992322354 creator A5077294590 @default.
- W1992322354 date "2001-05-18" @default.
- W1992322354 modified "2023-10-11" @default.
- W1992322354 title "Metal-Modified Nucleobase Pairs and Triplets as Cytosine Receptors" @default.
- W1992322354 cites W1539796472 @default.
- W1992322354 cites W1963707557 @default.
- W1992322354 cites W1964277385 @default.
- W1992322354 cites W1975559577 @default.
- W1992322354 cites W1976337027 @default.
- W1992322354 cites W1977730605 @default.
- W1992322354 cites W1980930000 @default.
- W1992322354 cites W1986418242 @default.
- W1992322354 cites W1986800116 @default.
- W1992322354 cites W1993210268 @default.
- W1992322354 cites W1994240897 @default.
- W1992322354 cites W1997008091 @default.
- W1992322354 cites W1997230427 @default.
- W1992322354 cites W1997283810 @default.
- W1992322354 cites W1997811517 @default.
- W1992322354 cites W1998191742 @default.
- W1992322354 cites W1999439772 @default.
- W1992322354 cites W2000122226 @default.
- W1992322354 cites W2001138065 @default.
- W1992322354 cites W2004855176 @default.
- W1992322354 cites W2005537504 @default.
- W1992322354 cites W2006091250 @default.
- W1992322354 cites W2013204370 @default.
- W1992322354 cites W2014872415 @default.
- W1992322354 cites W2018239196 @default.
- W1992322354 cites W2020830289 @default.
- W1992322354 cites W2021920164 @default.
- W1992322354 cites W2022972576 @default.
- W1992322354 cites W2026129927 @default.
- W1992322354 cites W2026199597 @default.
- W1992322354 cites W2030219041 @default.
- W1992322354 cites W2030419816 @default.
- W1992322354 cites W2032811669 @default.
- W1992322354 cites W2034277646 @default.
- W1992322354 cites W2035009750 @default.
- W1992322354 cites W2037747457 @default.
- W1992322354 cites W2038881834 @default.
- W1992322354 cites W2041582325 @default.
- W1992322354 cites W2041695980 @default.
- W1992322354 cites W2042561749 @default.
- W1992322354 cites W2043504820 @default.
- W1992322354 cites W2047746503 @default.
- W1992322354 cites W2051478599 @default.
- W1992322354 cites W2054446384 @default.
- W1992322354 cites W2062326564 @default.
- W1992322354 cites W2064679163 @default.
- W1992322354 cites W2070588093 @default.
- W1992322354 cites W2073778174 @default.
- W1992322354 cites W2073783137 @default.
- W1992322354 cites W2074645407 @default.
- W1992322354 cites W2074984651 @default.
- W1992322354 cites W2083530330 @default.
- W1992322354 cites W2084310019 @default.
- W1992322354 cites W2088371430 @default.
- W1992322354 cites W2089300606 @default.
- W1992322354 cites W2089706993 @default.
- W1992322354 cites W2094125817 @default.
- W1992322354 cites W2099361743 @default.
- W1992322354 cites W2113051856 @default.
- W1992322354 cites W2130033802 @default.
- W1992322354 cites W2134582575 @default.
- W1992322354 cites W2148066840 @default.
- W1992322354 cites W2150247785 @default.
- W1992322354 cites W2158709145 @default.
- W1992322354 cites W2169905012 @default.
- W1992322354 cites W2171679419 @default.
- W1992322354 cites W29179573 @default.
- W1992322354 cites W2950057322 @default.
- W1992322354 cites W2951440459 @default.
- W1992322354 cites W4205375190 @default.
- W1992322354 cites W4230103577 @default.
- W1992322354 cites W4244779104 @default.
- W1992322354 doi "https://doi.org/10.1002/1521-3765(20010518)7:10<2104::aid-chem2104>3.0.co;2-f" @default.
- W1992322354 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11411983" @default.
- W1992322354 hasPublicationYear "2001" @default.
- W1992322354 type Work @default.
- W1992322354 sameAs 1992322354 @default.
- W1992322354 citedByCount "35" @default.
- W1992322354 countsByYear W19923223542012 @default.
- W1992322354 countsByYear W19923223542013 @default.
- W1992322354 countsByYear W19923223542015 @default.
- W1992322354 countsByYear W19923223542016 @default.
- W1992322354 countsByYear W19923223542017 @default.
- W1992322354 countsByYear W19923223542018 @default.
- W1992322354 countsByYear W19923223542022 @default.
- W1992322354 crossrefType "journal-article" @default.
- W1992322354 hasAuthorship W1992322354A5027148319 @default.
- W1992322354 hasAuthorship W1992322354A5043059401 @default.
- W1992322354 hasAuthorship W1992322354A5077294590 @default.
- W1992322354 hasConcept C104317684 @default.