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- W1994081104 abstract "Abstract The precursors MH 2 (CO)(PPh 3 ) 3 (M = Ru or Os), Ru(CO) 3 (PPh 3 ) 2 /OsH 2 (CO) 2 (PPh 3 ) 2 and IrH(CO)(PPh 3 ) 3 react with 1,3,4-thiadiazole-2,5-dithiol (tddtH 2 ) in boilig toluene to afford the 1,3,4-thiadiazole-2,5-dithiolato (tddtH) complexes M(tddtH) 2 (CO)(PPh 3 ) 2 , M(tddtH) 2 (CO) 2 (PPh 3 ) 2 and IrH(tddtH) 2 (CO)(PPh 3 ) 2 respectively. The molecular structure of the ruthenium complex Ru(tddtH) 2 (CO)(PPh 3 ) 2 has been determined by X-ray diffraction methods, the crystals are triclinic space group P 1 , Z = 2, unit cell dimensions are a = 13.051(3), b = 16.404(7), c = 16.500(5) A, α = 119.60(2), β = 91.46(2), γ = 104.21(3)°, ( V = 2932.0(16) A 3 . The structure contains octahedral ruthenium(II) with mon-dentate (S-coordinated) and bi-dentate (N,S-coordinated) tddtH ligands, a carbonyl group and a trans pair of triphenylphosphine ligands. The complexes M(tddtH) 2 (CO)(PPh 3 ) 2 and the closely related ruthenium 5-methyl-1,3,4-thiadiazole 2-thiolato complex Ru(mtdt) 2 (CO)(PPh 3 ) 2 have been shown by 1 H NMR to display dynamic interchange of mono- and bi-dentate thiolate ligands. Some rhodium(I), palladium(0) and platinum(0) complexes of tddtH 2 are tentatively reformulated." @default.
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- W1994081104 title "1,3,4,-Thiadiazole-2,5-dithiol complexes of the platinum group metals; the molecular structure of carbonylbis(1,3,4-thiadiazole-2,5-dithiolato)bis(triphenylphosphine)ruthenium(II)" @default.
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- W1994081104 doi "https://doi.org/10.1016/s0020-1693(00)87988-8" @default.
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