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- W1998607918 abstract "Abstract ( R )‐ or ( S )‐BINOLAM‐AlCl, generated in situ, work as bifunctional catalysts in promoting the enantioselective cyanoalkoxycarbonylation of aldehydes. The reaction is wide in scope and the mechanistic evidence gathered suggests the intervention of an indirect process involving enantioselective hydrocyanation by HCN, followed by O ‐alkoxycarbonylation. The resultant O ‐alkoxycarbonyl cyanohydrins are shown to be important chiral building blocks for synthesis. Chemoselective hydrolysis can thus be directed either to provide enantioenriched β‐hydroxy esters, or acids, or instead to give O ‐methoxycarbonyl β‐hydroxy acids, esters, or amides. In addition, the enantiopure cyanocarbonates can be converted into β‐amino alcohols by reduction with lithiumaluminium hydride. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
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- W1998607918 date "2006-03-28" @default.
- W1998607918 modified "2023-10-18" @default.
- W1998607918 title "Enantioselective Synthesis of <i>O</i>‐Methoxycarbonyl Cyanohydrins: Chiral Building Blocks Generated by Bifunctional Catalysis with BINOLAM‐AlCl" @default.
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- W1998607918 doi "https://doi.org/10.1002/ejoc.200500939" @default.
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