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- W1999221413 abstract "Off-center impurity ions in solids often perform rotations around their regular lattice sites. Unlike quasifree rotors with rotational line spectra subject to textbook attention in quantum mechanics, the off-center species are hindered rotors with spectra quantized in rotational bands. These bands occur because of tunneling through barriers arising along the orbital path. For an off-center ion rotating along a planar orbit, such as the Li+ impurity nearest-neighboring an F center in alkali halide, the hindered rotation will give rise to specific magnetic moments that couple to and quantize external magnetic fields normal to the orbital plane. We present a simple theory and estimates of Li+ magnetic dipoles and rotational bands to find conditions for an experimental verification. © 2002 Wiley Periodicals, Inc. Int J Quantum Chem, 2002" @default.
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- W1999221413 date "2002-01-01" @default.
- W1999221413 modified "2023-09-27" @default.
- W1999221413 title "Magnetic moments of hindered rotators by off-center impurity ions" @default.
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- W1999221413 doi "https://doi.org/10.1002/qua.10287" @default.
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