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• W2000305637 abstract "In diethyl ether, N-Boc-2-lithio-2-arylpiperidines have been found to be configurationally stable at −80 °C, whereas N-Boc-2-lithio-2-arylpyrrolidines are configurationally stable at −60 °C. Several tertiary benzylic carbanions derived from enantioenriched 2-aryl heterocycles have been successfully alkylated or acylated with little to no loss of enantiopurity. The scope of the reactions has been explored. The enantiomerization dynamics of N-Boc-2-lithio-2-phenylpyrrolidine and N-Boc-2-lithio-2-phenylpiperidine have been studied in the presence of different solvents and achiral ligands." @default.
• W2000305637 created "2016-06-24" @default.
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• W2000305637 date "2012-08-27" @default.
• W2000305637 modified "2023-10-07" @default.
• W2000305637 title "Synthetic Applications and Inversion Dynamics of Configurationally Stable 2-Lithio-2-arylpyrrolidines and -piperidines" @default.
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• W2000305637 doi "https://doi.org/10.1021/ja306276w" @default.
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