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- W2000865186 abstract "Low-wavenumber Raman spectra of oreinted single crystals of fourteen caesium alums are reported and analysed. Assignments have been made based on (i) selenate for sulfate substitution; (ii) deuteriation; (iii) change in the strength of the hydrogen bonding caused by a change in the alum type; and (iv) isomorphous substitution of the tervalent metal cation. The observed modes comprise the translation and rotation of the sulfate (or selenate) anions, the rotations of the hexa-aqua-caesium cation and the hexa-aqua-metal(III) cation, and the internal modes of the hexa-aqua-caesium cation. The key to the assignment of the spectra is the observation of all six of the Eg modes and most of the Ag modes predicted from the factor group analysis. The Fg modes are then assigned by association with the Eg modes." @default.
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- W2000865186 date "1996-05-01" @default.
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- W2000865186 title "Assignment of the low-wavenumber single-crystal Raman spectra of the caesium alums between 10 and 275 cm−1" @default.
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- W2000865186 doi "https://doi.org/10.1016/0584-8539(95)01588-4" @default.
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