Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001397478> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2001397478 endingPage "192" @default.
- W2001397478 startingPage "177" @default.
- W2001397478 abstract "The equilibrium formation constants of manganese(II) chloride complexes have been determined spectrophotometrically in the temperature range from 25°C to 300°C at saturated water vapour pressure at chloride concentrations from 0.022 to 0.80 mol kg−1. Mn2+ and MnCl+ were the only species identified at temperatures from 25°C to 100°C. From 150°C to 300°C, the uncharged MnCl20 complex was identified and it becomes the predominant species in concentrated chloride solutions at T≥300°C. It is of interest to note that both MnCl+ and MnCl20 increase considerably in stability with increasing temperature. From 25°C to 300°C, logβ1 increases from 0.85 (±0.08) to 4.21(±0.12) and from 150°C to 300°C, logβ2 changes from 0.88 (±0.10) to 4.63 (±0.15). With increasing temperature from 25°C to 300°C, the formation of MnCl+ is characterised by increasingly endothermic enthalpies and large positive entropies, indicative of greater electrostatic interaction. Chloride complexes will play an important role in the transport and deposition chemistry of manganese by hydrothermal fluids migrating through the earth's crust." @default.
- W2001397478 created "2016-06-24" @default.
- W2001397478 creator A5079461540 @default.
- W2001397478 creator A5082606314 @default.
- W2001397478 date "2000-06-01" @default.
- W2001397478 modified "2023-10-16" @default.
- W2001397478 title "Spectrophotometric measurements of metal complex formation at high temperatures: the stability of Mn(II) chloride species" @default.
- W2001397478 cites W1968313831 @default.
- W2001397478 cites W1972070662 @default.
- W2001397478 cites W1977867457 @default.
- W2001397478 cites W1980383266 @default.
- W2001397478 cites W1999918423 @default.
- W2001397478 cites W2002296530 @default.
- W2001397478 cites W2009263138 @default.
- W2001397478 cites W2011021696 @default.
- W2001397478 cites W2011521280 @default.
- W2001397478 cites W2018820772 @default.
- W2001397478 cites W2023068468 @default.
- W2001397478 cites W2030393460 @default.
- W2001397478 cites W2034748594 @default.
- W2001397478 cites W2045731375 @default.
- W2001397478 cites W2058766773 @default.
- W2001397478 cites W2061083615 @default.
- W2001397478 cites W2066812259 @default.
- W2001397478 cites W2314548050 @default.
- W2001397478 doi "https://doi.org/10.1016/s0009-2541(00)00193-5" @default.
- W2001397478 hasPublicationYear "2000" @default.
- W2001397478 type Work @default.
- W2001397478 sameAs 2001397478 @default.
- W2001397478 citedByCount "38" @default.
- W2001397478 countsByYear W20013974782012 @default.
- W2001397478 countsByYear W20013974782013 @default.
- W2001397478 countsByYear W20013974782014 @default.
- W2001397478 countsByYear W20013974782015 @default.
- W2001397478 countsByYear W20013974782016 @default.
- W2001397478 countsByYear W20013974782018 @default.
- W2001397478 countsByYear W20013974782020 @default.
- W2001397478 countsByYear W20013974782021 @default.
- W2001397478 countsByYear W20013974782023 @default.
- W2001397478 crossrefType "journal-article" @default.
- W2001397478 hasAuthorship W2001397478A5079461540 @default.
- W2001397478 hasAuthorship W2001397478A5082606314 @default.
- W2001397478 hasConcept C10710636 @default.
- W2001397478 hasConcept C121332964 @default.
- W2001397478 hasConcept C127313418 @default.
- W2001397478 hasConcept C147789679 @default.
- W2001397478 hasConcept C150394285 @default.
- W2001397478 hasConcept C156622251 @default.
- W2001397478 hasConcept C165205528 @default.
- W2001397478 hasConcept C168191866 @default.
- W2001397478 hasConcept C178790620 @default.
- W2001397478 hasConcept C179104552 @default.
- W2001397478 hasConcept C184651966 @default.
- W2001397478 hasConcept C185592680 @default.
- W2001397478 hasConcept C20976626 @default.
- W2001397478 hasConcept C2778695967 @default.
- W2001397478 hasConcept C39353612 @default.
- W2001397478 hasConcept C528890316 @default.
- W2001397478 hasConcept C544153396 @default.
- W2001397478 hasConcept C97355855 @default.
- W2001397478 hasConceptScore W2001397478C10710636 @default.
- W2001397478 hasConceptScore W2001397478C121332964 @default.
- W2001397478 hasConceptScore W2001397478C127313418 @default.
- W2001397478 hasConceptScore W2001397478C147789679 @default.
- W2001397478 hasConceptScore W2001397478C150394285 @default.
- W2001397478 hasConceptScore W2001397478C156622251 @default.
- W2001397478 hasConceptScore W2001397478C165205528 @default.
- W2001397478 hasConceptScore W2001397478C168191866 @default.
- W2001397478 hasConceptScore W2001397478C178790620 @default.
- W2001397478 hasConceptScore W2001397478C179104552 @default.
- W2001397478 hasConceptScore W2001397478C184651966 @default.
- W2001397478 hasConceptScore W2001397478C185592680 @default.
- W2001397478 hasConceptScore W2001397478C20976626 @default.
- W2001397478 hasConceptScore W2001397478C2778695967 @default.
- W2001397478 hasConceptScore W2001397478C39353612 @default.
- W2001397478 hasConceptScore W2001397478C528890316 @default.
- W2001397478 hasConceptScore W2001397478C544153396 @default.
- W2001397478 hasConceptScore W2001397478C97355855 @default.
- W2001397478 hasIssue "1-2" @default.
- W2001397478 hasLocation W20013974781 @default.
- W2001397478 hasOpenAccess W2001397478 @default.
- W2001397478 hasPrimaryLocation W20013974781 @default.
- W2001397478 hasRelatedWork W1992287265 @default.
- W2001397478 hasRelatedWork W1996548961 @default.
- W2001397478 hasRelatedWork W2009359832 @default.
- W2001397478 hasRelatedWork W2332056428 @default.
- W2001397478 hasRelatedWork W2349657250 @default.
- W2001397478 hasRelatedWork W2380273243 @default.
- W2001397478 hasRelatedWork W2801040395 @default.
- W2001397478 hasRelatedWork W3122370993 @default.
- W2001397478 hasRelatedWork W4205814902 @default.
- W2001397478 hasRelatedWork W4210628558 @default.
- W2001397478 hasVolume "167" @default.
- W2001397478 isParatext "false" @default.
- W2001397478 isRetracted "false" @default.
- W2001397478 magId "2001397478" @default.
- W2001397478 workType "article" @default.