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- W2004637963 abstract "Abstract Vibrational spectra for several potassium para-substituted tetraarylborate compounds: KB(C 6 H 4 p -X) 4 , where X is H, OCH 3 , CH 3 , Br, Cl, F, CF 3 , have been obtained in the solid state from 4000 to 200 cm −1 . Emphasis is placed on the X-sensitive modes located between 650 and 200 cm −1 because they are found to react to electronic substituent effects. The parent molecule, potassium tetraphenylborate, is discussed in detail within this region. Tentative assignments are made for absorptions arising from the low frequency phenyl ring modes, vibrations of the tetrahedral skeleton, ionic lattice vibrations, and vibrations that are either internal vibrations of the para -substituent group or vibrations involving the ring-substituent bond. However, these spectra do not yield any information on the electron densities in the vicinity of the central boron atom within these tetraarylborate anions." @default.
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- W2004637963 date "1971-03-01" @default.
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- W2004637963 title "Vibrational spectra of several potassium para-substituted tetraarylborates" @default.
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- W2004637963 doi "https://doi.org/10.1016/0584-8539(71)80056-9" @default.
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