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- W2005642069 abstract "The ring opening of various epoxides was achieved under mild conditions using bismuth(III) salts. Halohydrins and β-hydroxy nitrates were efficiently obtained from the corresponding 5α,6α-, 2α,3α-, and 5β,6β-epoxysteroid using BiCl3, BiBr3 or Bi(NO3)3·5H2O. Considerations about the probable reaction mechanism are provided. 2D homo- and heteronuclear correlation NMR spectroscopic techniques were used to unequivocally demonstrate the trans-diaxial nature of the epoxide ring opening." @default.
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- W2005642069 date "2007-09-01" @default.
- W2005642069 modified "2023-10-02" @default.
- W2005642069 title "Bismuth(III) salts mediated regioselective ring opening of epoxides: an easy route to halohydrins and β-hydroxy nitrates" @default.
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- W2005642069 doi "https://doi.org/10.1016/j.tet.2007.06.054" @default.
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