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• W2007008809 abstract "The thermal behaviors of polystyrene (PS)/triphenylmethyl chloride (TPCM) blends with different polymer molecular weights were investigated through differential scanning colorimetry (DSC). It was shown that when solvent content was lower than a critical composition, there was only a single amorphous phase in the blends. With increasing polymer concentration, both Tg and Tm could be detected in DSC curves, revealing that the blends were heterogeneous. The constant Tg of the amorphous phase indicated that the composition of the amorphous phase in the blends did not depend on the solvent concentration, and the Tm depression with decreasing PS content showed the decrease of TPCM crystallite size owing to geometric constraint by the polymer chains. On the basis of the Flory–Huggins theory, the interaction parameters between PS and TPCM in the blends were obtained; they showed that the PS/TPCM blends were not thermodynamically miscible with low polymer content. The Hoffmann-Weeks equation indicated that the crystals corresponding to the lower melting point were unstable. The unstable crystals in the blends were located in the interfacial regions between the crystalline solvent molecules and the amorphous phase. The heat capacity of the blends confirmed the geometric constraint on the crystallization of TPCM in the blends." @default.
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• W2007008809 date "2011-05-27" @default.
• W2007008809 modified "2023-10-16" @default.
• W2007008809 title "Thermal Behaviors of Confined Triphenylmethyl Chloride Crystals in Various Molecular Weight Polystyrene" @default.
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• W2007008809 doi "https://doi.org/10.1080/00222348.2010.516710" @default.
• W2007008809 hasPublicationYear "2011" @default.
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