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- W2007181281 abstract "Ion-exchange of Na56Y with Cs+ cations has been monitored by 133Cs MAS NMR. The observed signals are assigned to the extraframework cation sites based on the incremental ion-exchange process, as well as the adsorption of the tungsten hexacarbonyl molecule, W(CO)6. The latter process selectively shifts the signals of α-cage Cs+ ions in the zeolite host. Subsequent oxidation of adsorbed W(CO)6 to form encapsulated tungsten(VI) oxide also has a strong effect on the position and line width of the signals from the α-cage 133Cs+ ions. Because of the relatively low quadrupolar coupling of 133Cs nuclei in Na(56-x)CsxY, their MAS signals do not suffer from extensive second-order broadening, as is the case of 23Na nuclei. Therefore, 133Cs MAS can be usefully applied to study zeolite ion-exchange and adsorption processes." @default.
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- W2007181281 date "1996-01-01" @default.
- W2007181281 modified "2023-09-25" @default.
- W2007181281 title "Probing Cation Sites in Cesium-Exchanged Zeolite Y via <sup>133</sup>Cs MAS NMR" @default.
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- W2007181281 doi "https://doi.org/10.1021/jp961265w" @default.
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