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- W2007755674 abstract "We have observed a previously unreported metastable intermediate phase during the crystallization of magnesium metaphosphate (Mg(PO3)2) glasses to the equilibrium ring phase, Mg2P4O12. Our current hypothesis is that the metastable phase contains metaphosphate chains, as in other crystalline alkaline-earth metaphosphates. This type of phase could form by low-energy rearrangement of the polyphosphate chains in the glass structure. Thus, its formation might be favored at low temperatures where there is insufficient thermal energy to break the metaphosphate chains and form tetrametaphosphate rings." @default.
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- W2007755674 modified "2023-09-26" @default.
- W2007755674 title "Metastable-Phase Formation During the Crystallization of Magnesium Metaphosphate Glass" @default.
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- W2007755674 doi "https://doi.org/10.1111/j.1151-2916.1990.tb06703.x" @default.
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