FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009036346> ?p ?o ?g. }

• W2009036346 endingPage "288" @default.
• W2009036346 startingPage "280" @default.
• W2009036346 abstract "Among a wide range of noncovalent interactions, hydrogen (H) bonds are well known for their specific roles in various chemical and biological phenomena. When describing conventional hydrogen bonding, researchers use the notation AH···D (where A refers to the electron acceptor and D to the donor). However, the AH molecule engaged in a AH···D H-bond can also be pivoted around by roughly 180°, resulting in a HA···D arrangement. Even without the H atom in a bridging position, this arrangement can be attractive, as explained in this Account. The electron density donated by D transfers into a AH σ* antibonding orbital in either case: the lobe of the σ* orbital near the H atom in the H-bonding AH···D geometry, or the lobe proximate to the A atom in the HA···D case. A favorable electrostatic interaction energy between the two molecules supplements this charge transfer. When A belongs to the pnictide family of elements, which include phosphorus, arsenic, antimony, and bismuth, this type of interaction is called a pnicogen bond. This bonding interaction is somewhat analogous to the chalcogen and halogen bonds that arise when A is an element in group 16 or 17, respectively, of the periodic table.Electronegative substitutions, such as a F for a H atom opposite the electron donor atom, strengthen the pnicogen bond. For example, the binding energy in FH2P···NH3 greatly exceeds that of the paradigmatic H-bonding water dimer. Surprisingly, di- or tri-halogenation does not produce any additional stabilization, in marked contrast to H-bonds. Chalcogen and halogen bonds show similar strength to the pnicogen bond for a given electron-withdrawing substituent. This insensitivity to the electron-acceptor atom distinguishes these interactions from H-bonds, in which energy depends strongly upon the identity of the proton-donor atom.As with H-bonds, pnicogen bonds can extract electron density from the lone pairs of atoms on the partner molecule, such as N, O, and S. The π systems of carbon chains can donate electron density in pnicogen bonds. Indeed, the strength of A···π pnicogen bonds exceeds that of H-bonds even when using strong proton donors such as water with the same π system.H-bonds typically have a high propensity for a linear AH···D arrangement, but pnicogen bonds show an even greater degree of anisotropy. Distortions of pnicogen bonds away from their preferred geometry cause a more rapid loss of stability than in H-bonds. Although often observed in dimers in the gas phase, pnicogen bonds also serve as the glue in larger aggregates, and researchers have found them in a number of diffraction studies of crystals." @default.
• W2009036346 created "2016-06-24" @default.
• W2009036346 creator A5085422555 @default.
• W2009036346 date "2012-11-07" @default.
• W2009036346 modified "2023-10-16" @default.
• W2009036346 title "The Pnicogen Bond: Its Relation to Hydrogen, Halogen, and Other Noncovalent Bonds" @default.
• W2009036346 cites W1590976469 @default.
• W2009036346 cites W1645290768 @default.
• W2009036346 cites W1964004579 @default.
• W2009036346 cites W1965858810 @default.
• W2009036346 cites W1967521726 @default.
• W2009036346 cites W1967912156 @default.
• W2009036346 cites W1968819963 @default.
• W2009036346 cites W1971163225 @default.
• W2009036346 cites W1971413830 @default.
• W2009036346 cites W1972185088 @default.
• W2009036346 cites W1972764077 @default.
• W2009036346 cites W1973239710 @default.
• W2009036346 cites W1979074086 @default.
• W2009036346 cites W1983043365 @default.
• W2009036346 cites W1989211016 @default.
• W2009036346 cites W1995824433 @default.
• W2009036346 cites W2006728016 @default.
• W2009036346 cites W2012399256 @default.
• W2009036346 cites W2018398804 @default.
• W2009036346 cites W2026352622 @default.
• W2009036346 cites W2030478221 @default.
• W2009036346 cites W2037836900 @default.
• W2009036346 cites W2039461296 @default.
• W2009036346 cites W2039735251 @default.
• W2009036346 cites W2042646683 @default.
• W2009036346 cites W2045530301 @default.
• W2009036346 cites W2049844892 @default.
• W2009036346 cites W2062794438 @default.
• W2009036346 cites W2065867563 @default.
• W2009036346 cites W2065924010 @default.
• W2009036346 cites W2078641649 @default.
• W2009036346 cites W2080748295 @default.
• W2009036346 cites W2080796053 @default.
• W2009036346 cites W2094319104 @default.
• W2009036346 cites W2119580673 @default.
• W2009036346 cites W2131214655 @default.
• W2009036346 cites W2133122941 @default.
• W2009036346 cites W2133784816 @default.
• W2009036346 cites W2138841461 @default.
• W2009036346 cites W2166956719 @default.
• W2009036346 cites W2313123091 @default.
• W2009036346 cites W2314004643 @default.
• W2009036346 cites W2314007784 @default.
• W2009036346 cites W2316473861 @default.
• W2009036346 cites W2331968740 @default.
• W2009036346 cites W2949600758 @default.
• W2009036346 cites W4233828289 @default.
• W2009036346 cites W4300611374 @default.
• W2009036346 doi "https://doi.org/10.1021/ar3001316" @default.
• W2009036346 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23135342" @default.
• W2009036346 hasPublicationYear "2012" @default.
• W2009036346 type Work @default.
• W2009036346 sameAs 2009036346 @default.
• W2009036346 citedByCount "492" @default.
• W2009036346 countsByYear W20090363462013 @default.
• W2009036346 countsByYear W20090363462014 @default.
• W2009036346 countsByYear W20090363462015 @default.
• W2009036346 countsByYear W20090363462016 @default.
• W2009036346 countsByYear W20090363462017 @default.
• W2009036346 countsByYear W20090363462018 @default.
• W2009036346 countsByYear W20090363462019 @default.
• W2009036346 countsByYear W20090363462020 @default.
• W2009036346 countsByYear W20090363462021 @default.
• W2009036346 countsByYear W20090363462022 @default.
• W2009036346 countsByYear W20090363462023 @default.
• W2009036346 crossrefType "journal-article" @default.
• W2009036346 hasAuthorship W2009036346A5085422555 @default.
• W2009036346 hasConcept C112887158 @default.
• W2009036346 hasConcept C121332964 @default.
• W2009036346 hasConcept C130188946 @default.
• W2009036346 hasConcept C137277065 @default.
• W2009036346 hasConcept C147120987 @default.
• W2009036346 hasConcept C147597530 @default.
• W2009036346 hasConcept C149635348 @default.
• W2009036346 hasConcept C152365726 @default.
• W2009036346 hasConcept C158733187 @default.
• W2009036346 hasConcept C159467904 @default.
• W2009036346 hasConcept C178790620 @default.
• W2009036346 hasConcept C185592680 @default.
• W2009036346 hasConcept C189394030 @default.
• W2009036346 hasConcept C192095803 @default.
• W2009036346 hasConcept C23029723 @default.
• W2009036346 hasConcept C26873012 @default.
• W2009036346 hasConcept C2779892579 @default.
• W2009036346 hasConcept C32909587 @default.
• W2009036346 hasConcept C41008148 @default.
• W2009036346 hasConcept C54101563 @default.
• W2009036346 hasConcept C58312451 @default.
• W2009036346 hasConcept C62520636 @default.
• W2009036346 hasConcept C63385615 @default.
• W2009036346 hasConcept C8010536 @default.
• W2009036346 hasConcept C95269574 @default.

• next