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- W2014027841 abstract "Abstract The polarization of three low energy-singlet-singlet electronic transitions of several mono-substituted naphthalenes have been measured relative to the transition moment of fluorescence by the method of photoselection. It is shown that substitution of a hydroxy or a methoxy group at the 2 (orβ)-position of naphthalene leads to mixing between the 1 L b and 1 L a states, resulting in the short-axis polarization of the electronic transition to the former state. 1 (or α)- substituted compound exhibit no such mixing, and the transition to the 1 L b state is polarized largely along the long axis of the molecule. Substitution of a cyano group at the 2-position also leads to short-axis polarization of the L b band. These results are consistent with the predictions based on molecular orbital calculations." @default.
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- W2014027841 date "1972-12-01" @default.
- W2014027841 modified "2023-09-27" @default.
- W2014027841 title "Polarization of singlet-singlet electronic transitions in substituted naphtahlenes" @default.
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- W2014027841 doi "https://doi.org/10.1016/0009-2614(72)87098-2" @default.
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