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- W2015496040 abstract "The purpose of this study has been to study the flow behavior of several polystyrene samples ranging in molecular weight between 1 × 105 and 2 × 101 in several solvents. Intrinsic viscosities corrected for shear effects have been obtained according to several treatments already described in the literature. The results obtained show considerable divergences. The flow behavior of the samples was then studied from a rheological point of view; it is shown that the solutions are more and more Newtonian, the nearer they approach to zero shear stress. Interpretations of the viscosity plots are given. As a consequence, extrapolation of the viscosity curves obtained at very low shear stresses with the use of a special capillary viscometef to zero shear is considered to be the most convenient way of obtaining intrinsic viscosities corrected for shear; such a method is described. The results, in some cases, may be up to 60%, larger than the highest value obtained by the classical methods. The influence of solvent and molecular weight on this shear effect is also considered, and the whole situation is considered, taking into account the possible “structure” of the solutions and the nature of the polymers." @default.
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- W2015496040 date "1959-03-01" @default.
- W2015496040 modified "2023-10-04" @default.
- W2015496040 title "Influence of the velocity gradient on the viscosity of polystyrene solutions" @default.
- W2015496040 doi "https://doi.org/10.1002/pol.1959.1203512912" @default.
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