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- W2016995513 abstract "The oxidation of the following derivatives has been studied by cyclic voltammetry in tetrahydrofuran solvent at a platinum electrode: (Et3P)2M(η2 − C60), [(Et3P)2M]6C60) (M = Pt, Pd, Ni, Et = ethyl) and [(Et3P)2Pt]nC60 (n = 2–4). The derivatives containing one organometallic group are oxidized in a two-electron irreversible reaction that cleaves off the metal fragment giving free C60. As additional platinum-containing groups are added in the series [(Et3P)2Pt]nC60 (n = 1–4), the complexes become successively more easily oxidized. For n = 2 and n = 3, the first step of oxidation involves cleavage of the addend giving the next lower complex until, at the most positive peak, C60 is produced. For [(Et3P)2Pt]4C60, the first step of oxidation is a one-electron process that shows some chemical reversibility. A second irreversible step may represent a second step of oxidation or be due to a different isomer. The previously reported anodic peak potentials for the complexes n = 1–6, M = Pt, Pd, Ni, vary linearly with n. The sensitivity of the peak potentials to the number of addends is discussed with reference to similar effects seen for the reversible reduction potentials." @default.
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- W2016995513 title "Voltammetric study of the oxidation of metal derivatives of buckminsterfullerence (C60)" @default.
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- W2016995513 doi "https://doi.org/10.1016/0022-0728(94)03630-l" @default.
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