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• W2017547247 abstract "The rotationally resolved spectra of the van der Waals complexes Ne-N2O, Kr-N2O, and Xe-N2O have been investigated in the region of the nu3 N2O monomer vibrational band using a diode laser absorption spectrometer that is incorporated with a multipass cell and a pulsed jet. The spectra of these three complexes are completely analyzed using a normal asymmetric rotor Hamiltonian, and the effective molecular constants are accurately determined for both the ground and the excited vibrational states. These results show that, like Ar-N2O, the complexes have a T-shaped configuration in which the rare gas atom prefers to lie near to the oxygen side of N2O. The band origins of Rg-N2O (Rg = Ne, Ar, Kr, and Xe) are observed to shift by 0.36125, 0.15038, -0.10131, and -0.49066 cm-1 from that of the monomer, respectively. These band origin shifts are well explained by a simple model for the intermolecular potential. Copyright 1998 Academic Press." @default.
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• W2017547247 date "1998-06-01" @default.
• W2017547247 modified "2023-10-18" @default.
• W2017547247 title "High-Resolution Infrared Diode Laser Spectroscopy of Ne–N2O, Kr–N2O, and Xe–N2O" @default.
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• W2017547247 doi "https://doi.org/10.1006/jmsp.1998.7550" @default.
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