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• W2020094039 abstract "A pressure-induced amorphous-to-amorphous reversible transformation was revealed in Pr75Al25 metallic glass (MG) using in situ high-pressure synchrotron x-ray diffraction technique. The transition began at about 21 GPa with a ∼ 5% volume collapse and ended at about 35 GPa. This transition is reversible with hysteresis. Based on the high-pressure behaviors of Ce-based metallic glasses and Pr metal here, we suggest that the pressure-induced polyamorphic transition in Pr75Al25 MG stems from 4f-electron delocalization of Pr metal which leads to abrupt change in bond shortening. These results obtained here provide new insights into the underlying mechanism of the amorphous-to-amorphous phase transition in metallic glasses and will trigger more theoretical and experimental investigations for such transition." @default.
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• W2020094039 date "2013-12-06" @default.
• W2020094039 modified "2023-09-25" @default.
• W2020094039 title "Pressure-induced amorphous-to-amorphous reversible transformation in Pr₇₅Al₂₅" @default.
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• W2020094039 doi "https://doi.org/10.1063/1.4841035" @default.
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