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- W2021859601 abstract "Abstract The triplet lifetimes and luminescence quantum yields were measured for seven monochloroquinolines, 2-methyl-4-chloroquinoline, 2-chloro-4-methylquinoline and two monochloronaphthalenes in ethanol at 77 K. The positional dependence of the rate constants for the T 1 → S 0 transitions in the chloroquinolines and chloronaphthalenes were analysed using the Freed—Jortner model of the displaced potential functions for aromatic hydrocarbons. The energy gap dependence of the radiationless transition was found to be very important for the discussion of the internal heavy-atom effect. The relation between theory and experiment is satisfactory when the CH out-of-plane vibrations are chosen as promoting modes for the relaxation of the triplet state for monochloroquinolines." @default.
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- W2021859601 date "1983-09-01" @default.
- W2021859601 modified "2023-10-17" @default.
- W2021859601 title "Internal heavy-atom effect on the T1 states of monochloroquinolines and monochloronaphthalenes" @default.
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- W2021859601 doi "https://doi.org/10.1016/0301-0104(83)85156-8" @default.
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