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- W2022201220 abstract "The fine structure theory of 4 Π states in diatomic molecules is reconsidered from the point of view of exact numerical diagonalization of the four-by-four perturbation matrix. The interaction with other electronic states is accounted for through a second order Van Vleck transformation. Centrifugal distortion corrections are also added to the matrix elements, and a new spin-spin matrix element of the type ΔΛ = -ΔΣ = ±2 is in particular found to contribute to the Λ-doubling. The theoretical results are applied to the a 4 Π u state in O 2 + and the B 4 Π state in VO." @default.
- W2022201220 created "2016-06-24" @default.
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- W2022201220 date "1975-09-01" @default.
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- W2022201220 title "Fine Structure of <sup>4</sup>Π States in Diatomic Molecules" @default.
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- W2022201220 doi "https://doi.org/10.1088/0031-8949/12/3/004" @default.
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