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- W2022634585 abstract "A state-of-the-art FFT-instrument recently described in this journal (which measures the impedance at each dc potential applied to a working electrode) was shown to perform with excellent precision in a kinetic study at a carbon fibre microelectrode. A constant phase element (CPE) was used in a model in order to correct for double layer effects arising at the carbon fibre microelectrode (∼11 μm). This simple model in combination with the data collected by the FFT-instrument were then used in order to determine the heterogeneous rate constant for a well-defined red/ox couple. Good agreement with previously published values was obtained." @default.
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- W2022634585 date "2000-11-01" @default.
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- W2022634585 title "Method for determination of heterogeneous rate constants at carbon-fibre microelectrodes using multi-ac-voltammetry" @default.
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- W2022634585 doi "https://doi.org/10.1016/s1388-2481(00)00123-5" @default.
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