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• W2022757366 abstract "A CN− adlayer on an electrochemical Pt surface produces two detectable vibrational bands. The band at 2160 cm−1 has previously been assigned to an intermediate species in the electrochemical production of [Pt(CN)4]2−. The second mode (≈2100–2140 cm−1) is attributed to a co-adsorbed cyanide monolayer. The lifetime of the 2160 cm−1 mode is ≈4–6 ps at potentials where the two modes are close in energy and approaches that of freely solvated cyanide ions (≈30 ps) at potentials where the two modes become well separated in energy. This potential dependence is interpreted in the context of a simple dipole–dipole coupling mechanism." @default.
• W2022757366 created "2016-06-24" @default.
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• W2022757366 date "2001-05-01" @default.
• W2022757366 modified "2023-10-18" @default.
• W2022757366 title "Intermolecular vibrational energy transfer between cyanide species at the platinum/electrolyte interface" @default.
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• W2022757366 doi "https://doi.org/10.1016/s0009-2614(01)00405-5" @default.
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