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• W2023274649 abstract "New bidentate monosulfonated diamines, with an axially chiral biaryl backbone in combination with different Ir(III) complexes, were investigated in the catalytic transfer hydrogenation of acetophenone under i-PrOH/i-PrOK conditions. The resulting catalysts showed a strong, unexpected, and unusual base dependent enantioselectivity. Less base than chiral catalyst resulted in an (R)-configured secondary alcohol, excess of base in the (S)-enantiomer, using (P)-configured ligands." @default.
• W2023274649 created "2016-06-24" @default.
• W2023274649 creator A5080159501 @default.
• W2023274649 creator A5083486032 @default.
• W2023274649 date "2005-12-01" @default.
• W2023274649 modified "2023-10-10" @default.
• W2023274649 title "Unusual base dependent enantioselectivity in a transfer hydrogenation using axially chiral Ir(III)-catalysts" @default.
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• W2023274649 doi "https://doi.org/10.1016/j.tetasy.2005.11.002" @default.
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