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• W2029168656 abstract "The thermal behaviour and morphology of a series of homogeneous ethylene–1-octene copolymers, covering a wide range of 1-octene content up to 44 mole%, is studied using differential scanning calorimetry (DSC), time-resolved small-angle X-ray scattering (SAXS) and wide-angle X-ray diffraction (WAXD). The influence of the comonomer (1-octene) content, as well as the influence of the comonomer type (branch length) are investigated by comparison with previous results on homogeneous ethylene–propylene and ethylene–1-butene copolymers. Special emphasis is put on copolymers with high comonomer contents or low densities (<870 kg/m3) at room temperature. The thermal behaviour and the morphology of the present copolymers reveal no discontinuities with increasing comonomer content and support a model in which the morphology changes gradually from a lamellar base morphology into a granular one consisting of small blocky structures and, possibly via fringed-micelles, into a morphology consisting of loosely packed ethylene sequences. The latter structures are too small and/or too imperfect to be detected by WAXD. However, SAXS and DSC are sensitive to them and are useful techniques over the whole comonomer content range." @default.
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• W2029168656 date "2000-06-01" @default.
• W2029168656 modified "2023-09-26" @default.
• W2029168656 title "Thermal behaviour and morphology of homogeneous ethylene–1-octene copolymers with high comonomer contents" @default.
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• W2029168656 doi "https://doi.org/10.1016/s0032-3861(99)00712-0" @default.
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