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- W2042384788 abstract "Die Aktivität des Komplexes CoH(N2)(PPh3)3 (1) liegt bei der CH-Aktivierung deutlich höher als beim Wilkinson-Katalysator. Noch effektiver wird aber eine Olefin-Isomerisierung induziert. Die zweistufige H-Abstraktion erfolgt beim 1,2-Dihydronaphthalin (2) cis-selektiv, der Primärschritt aber kaum regioselektiv. Hydrogen Transfer Reactions, 13. — Catalysis of Disproportionation by (Dinitrogen)hydridotris(triphenylphosphine)cobalt(I) For both CH activation and olefin isomerization, CoH(N2)(PPh3)3 (1) is a more powerful catalyst than the Wilkinson complex. In 1,2-dihydronaphthalene (2), a two-step cis abstraction of the hydrogen atoms is found with small regioselectivity in the first step." @default.
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- W2042384788 date "1989-10-01" @default.
- W2042384788 modified "2023-09-27" @default.
- W2042384788 title "Wasserstoffübertragungen, 13: (Distickstoff)hydridotris(triphenylphosphan)cobalt(I) als Disproportionierungs-Katalysator" @default.
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- W2042384788 doi "https://doi.org/10.1002/cber.19891221016" @default.
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