Matches in SemOpenAlex for { <https://semopenalex.org/work/W2050580020> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2050580020 endingPage "3663" @default.
- W2050580020 startingPage "3653" @default.
- W2050580020 abstract "The reaction of Lu3+ or Yb3+ and H5IO6 in aqueous media at 180 °C leads to the formation of Yb(IO3)3(H2O) or Lu(IO3)3(H2O), respectively, while the reaction of Yb metal with H5IO6 under similar reaction conditions gives rise to the anhydrous iodate, Yb(IO3)3. Under supercritical conditions Lu3+ reacts with HIO3 and KIO4 to yield the isostructural Lu(IO3)3. The structures have been determined by single-crystal X-ray diffraction. Crystallographic data are (MoKα, λ=0.71073 Å): Yb(IO3)3, monoclinic, space group P21/n, a=8.6664(9) Å, b=5.9904(6) Å, c=14.8826(15) Å, β=96.931(2)°, V=766.99(13), Z=4, R(F)=4.23% for 114 parameters with 1880 reflections with I>2σ(I); Lu(IO3)3, monoclinic, space group P21/n, a=8.6410(9), b=5.9961(6), c=14.8782(16) Å, β=97.028(2)°, V=765.08(14), Z=4, R(F)=2.65% for 119 parameters with 1756 reflections with I>2σ(I); Yb(IO3)3(H2O), monoclinic, space group C2/c, a=27.2476(15), b=5.6296(3), c=12.0157(7) Å, β=98.636(1)°, V=1822.2(2), Z=8, R(F)=1.51% for 128 parameters with 2250 reflections with I>2σ(I); Lu(IO3)3(H2O), monoclinic, space group C2/c, a=27.258(4), b=5.6251(7), c=12.0006(16) Å, β=98.704(2)°, V=1818.8(4), Z=8, R(F)=1.98% for 128 parameters with 2242 reflections with I>2σ(I). The f elements in all of the compounds are found in seven-coordinate environments and bridged with monodentate, bidentate, or tridentate iodate anions. Both Lu(IO3)3(H2O) and Yb(IO3)3(H2O) display distinctively different vibrational profiles from their respective anhydrous analogs. Hence, the Raman profile can be used as a complementary diagnostic tool to discern the different structural motifs of the compounds." @default.
- W2050580020 created "2016-06-24" @default.
- W2050580020 creator A5008566406 @default.
- W2050580020 creator A5025039459 @default.
- W2050580020 creator A5029749364 @default.
- W2050580020 creator A5051810231 @default.
- W2050580020 creator A5071251027 @default.
- W2050580020 date "2006-12-01" @default.
- W2050580020 modified "2023-10-16" @default.
- W2050580020 title "Syntheses, structures, and vibrational spectroscopy of the two-dimensional iodates Ln(IO3)3 and Ln(IO3)3(H2O) (LnYb, Lu)" @default.
- W2050580020 cites W160599597 @default.
- W2050580020 cites W1965215599 @default.
- W2050580020 cites W1969587122 @default.
- W2050580020 cites W1973214789 @default.
- W2050580020 cites W1978169499 @default.
- W2050580020 cites W1979001783 @default.
- W2050580020 cites W1979280319 @default.
- W2050580020 cites W1980719794 @default.
- W2050580020 cites W1998398170 @default.
- W2050580020 cites W1999706235 @default.
- W2050580020 cites W2005417326 @default.
- W2050580020 cites W2006500821 @default.
- W2050580020 cites W2009660930 @default.
- W2050580020 cites W2016329981 @default.
- W2050580020 cites W2021529158 @default.
- W2050580020 cites W2030246701 @default.
- W2050580020 cites W2042886286 @default.
- W2050580020 cites W2045352929 @default.
- W2050580020 cites W2045624630 @default.
- W2050580020 cites W2051748937 @default.
- W2050580020 cites W2052225712 @default.
- W2050580020 cites W2079867067 @default.
- W2050580020 cites W2101741054 @default.
- W2050580020 cites W2130980362 @default.
- W2050580020 cites W2133330879 @default.
- W2050580020 cites W2144332006 @default.
- W2050580020 cites W2950778106 @default.
- W2050580020 cites W2950961884 @default.
- W2050580020 cites W2952398229 @default.
- W2050580020 cites W2953069506 @default.
- W2050580020 cites W2953283983 @default.
- W2050580020 doi "https://doi.org/10.1016/j.jssc.2006.07.042" @default.
- W2050580020 hasPublicationYear "2006" @default.
- W2050580020 type Work @default.
- W2050580020 sameAs 2050580020 @default.
- W2050580020 citedByCount "20" @default.
- W2050580020 countsByYear W20505800202013 @default.
- W2050580020 countsByYear W20505800202014 @default.
- W2050580020 countsByYear W20505800202017 @default.
- W2050580020 countsByYear W20505800202018 @default.
- W2050580020 countsByYear W20505800202019 @default.
- W2050580020 countsByYear W20505800202021 @default.
- W2050580020 countsByYear W20505800202023 @default.
- W2050580020 crossrefType "journal-article" @default.
- W2050580020 hasAuthorship W2050580020A5008566406 @default.
- W2050580020 hasAuthorship W2050580020A5025039459 @default.
- W2050580020 hasAuthorship W2050580020A5029749364 @default.
- W2050580020 hasAuthorship W2050580020A5051810231 @default.
- W2050580020 hasAuthorship W2050580020A5071251027 @default.
- W2050580020 hasConcept C115624301 @default.
- W2050580020 hasConcept C178790620 @default.
- W2050580020 hasConcept C179104552 @default.
- W2050580020 hasConcept C185592680 @default.
- W2050580020 hasConcept C187714232 @default.
- W2050580020 hasConcept C205188671 @default.
- W2050580020 hasConcept C2778870691 @default.
- W2050580020 hasConcept C2780284529 @default.
- W2050580020 hasConcept C61276311 @default.
- W2050580020 hasConcept C8010536 @default.
- W2050580020 hasConceptScore W2050580020C115624301 @default.
- W2050580020 hasConceptScore W2050580020C178790620 @default.
- W2050580020 hasConceptScore W2050580020C179104552 @default.
- W2050580020 hasConceptScore W2050580020C185592680 @default.
- W2050580020 hasConceptScore W2050580020C187714232 @default.
- W2050580020 hasConceptScore W2050580020C205188671 @default.
- W2050580020 hasConceptScore W2050580020C2778870691 @default.
- W2050580020 hasConceptScore W2050580020C2780284529 @default.
- W2050580020 hasConceptScore W2050580020C61276311 @default.
- W2050580020 hasConceptScore W2050580020C8010536 @default.
- W2050580020 hasIssue "12" @default.
- W2050580020 hasLocation W20505800201 @default.
- W2050580020 hasOpenAccess W2050580020 @default.
- W2050580020 hasPrimaryLocation W20505800201 @default.
- W2050580020 hasRelatedWork W1982332453 @default.
- W2050580020 hasRelatedWork W2049749664 @default.
- W2050580020 hasRelatedWork W2089106763 @default.
- W2050580020 hasRelatedWork W2101143665 @default.
- W2050580020 hasRelatedWork W2141117312 @default.
- W2050580020 hasRelatedWork W2322937308 @default.
- W2050580020 hasRelatedWork W2804141023 @default.
- W2050580020 hasRelatedWork W2964153282 @default.
- W2050580020 hasRelatedWork W4284676956 @default.
- W2050580020 hasRelatedWork W2091271541 @default.
- W2050580020 hasVolume "179" @default.
- W2050580020 isParatext "false" @default.
- W2050580020 isRetracted "false" @default.
- W2050580020 magId "2050580020" @default.
- W2050580020 workType "article" @default.