Matches in SemOpenAlex for { <https://semopenalex.org/work/W2056226009> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2056226009 endingPage "1231" @default.
- W2056226009 startingPage "1219" @default.
- W2056226009 abstract "The infrared absorption spectra of finely powdered complex cobalt salts were obtained in the 2 to 15 micron region. Complexed ammonia shows four absorption bands, at approximately 3000, 1600, 1350, and 850 wave numbers. A possible assignment of three of these to N–H vibrations and the lowest to a rocking vibration, as proposed by Mizushima, is discussed. In the trisethylenediamine and hexanitrito complexes a frequency similar to the rocking vibration persists, but other frequencies characteristic of the particular ligands appear instead of N–H bands. A shift in the absorption maxima as the anions are changed shows that the fields of the anions are of importance. Fine structure observed in some of the strong absorption bands might be combinations with lattice vibrations. A comparison of the absorption spectra of certain hexammines obtained from deposited pure powders and from pressed KBr plates shows differences in details, which may be interpreted as indicating dissociation of the cobalt salt in the pressed KBr plate and an essentially liquid structure for the latter. The series of complex cobalt compounds whose infrared spectra were reported recently [D. G. Hill and A. F. Rosenberg, J. Chem. Phys. 22, 148 (1954)] has been extended to include a number of hexammines with various anions and several similar series of pentammines. A comparison has been made with a series of hexanitrito cobalt compounds and trisethylenediamine salts. The spectra of some of the compounds mentioned earlier have been remeasured and the range has been extended to the whole spectrum obtainable with a rocksalt prism. This has demonstrated greater complexity in the spectra than we had first imagined, but has led to a better understanding of them. Special care has been taken to insure the purity of all salts used." @default.
- W2056226009 created "2016-06-24" @default.
- W2056226009 creator A5067789589 @default.
- W2056226009 creator A5088553936 @default.
- W2056226009 date "1956-06-01" @default.
- W2056226009 modified "2023-09-25" @default.
- W2056226009 title "Infrared Absorption Spectra of Complex Cobalt Compounds" @default.
- W2056226009 cites W1966383866 @default.
- W2056226009 cites W2001482741 @default.
- W2056226009 cites W2014230665 @default.
- W2056226009 cites W2022494134 @default.
- W2056226009 cites W2031621595 @default.
- W2056226009 cites W2080026517 @default.
- W2056226009 cites W2093521587 @default.
- W2056226009 cites W2495233101 @default.
- W2056226009 doi "https://doi.org/10.1063/1.1742744" @default.
- W2056226009 hasPublicationYear "1956" @default.
- W2056226009 type Work @default.
- W2056226009 sameAs 2056226009 @default.
- W2056226009 citedByCount "30" @default.
- W2056226009 countsByYear W20562260092012 @default.
- W2056226009 countsByYear W20562260092015 @default.
- W2056226009 countsByYear W20562260092017 @default.
- W2056226009 countsByYear W20562260092020 @default.
- W2056226009 countsByYear W20562260092021 @default.
- W2056226009 countsByYear W20562260092022 @default.
- W2056226009 crossrefType "journal-article" @default.
- W2056226009 hasAuthorship W2056226009A5067789589 @default.
- W2056226009 hasAuthorship W2056226009A5088553936 @default.
- W2056226009 hasConcept C102931765 @default.
- W2056226009 hasConcept C11181451 @default.
- W2056226009 hasConcept C113196181 @default.
- W2056226009 hasConcept C119824511 @default.
- W2056226009 hasConcept C120665830 @default.
- W2056226009 hasConcept C121332964 @default.
- W2056226009 hasConcept C125287762 @default.
- W2056226009 hasConcept C1276947 @default.
- W2056226009 hasConcept C145148216 @default.
- W2056226009 hasConcept C147789679 @default.
- W2056226009 hasConcept C153642686 @default.
- W2056226009 hasConcept C158355884 @default.
- W2056226009 hasConcept C178790620 @default.
- W2056226009 hasConcept C179104552 @default.
- W2056226009 hasConcept C185592680 @default.
- W2056226009 hasConcept C191274033 @default.
- W2056226009 hasConcept C24169881 @default.
- W2056226009 hasConcept C26873012 @default.
- W2056226009 hasConcept C2992750936 @default.
- W2056226009 hasConcept C4839761 @default.
- W2056226009 hasConcept C515602321 @default.
- W2056226009 hasConcept C57805442 @default.
- W2056226009 hasConcept C8010536 @default.
- W2056226009 hasConceptScore W2056226009C102931765 @default.
- W2056226009 hasConceptScore W2056226009C11181451 @default.
- W2056226009 hasConceptScore W2056226009C113196181 @default.
- W2056226009 hasConceptScore W2056226009C119824511 @default.
- W2056226009 hasConceptScore W2056226009C120665830 @default.
- W2056226009 hasConceptScore W2056226009C121332964 @default.
- W2056226009 hasConceptScore W2056226009C125287762 @default.
- W2056226009 hasConceptScore W2056226009C1276947 @default.
- W2056226009 hasConceptScore W2056226009C145148216 @default.
- W2056226009 hasConceptScore W2056226009C147789679 @default.
- W2056226009 hasConceptScore W2056226009C153642686 @default.
- W2056226009 hasConceptScore W2056226009C158355884 @default.
- W2056226009 hasConceptScore W2056226009C178790620 @default.
- W2056226009 hasConceptScore W2056226009C179104552 @default.
- W2056226009 hasConceptScore W2056226009C185592680 @default.
- W2056226009 hasConceptScore W2056226009C191274033 @default.
- W2056226009 hasConceptScore W2056226009C24169881 @default.
- W2056226009 hasConceptScore W2056226009C26873012 @default.
- W2056226009 hasConceptScore W2056226009C2992750936 @default.
- W2056226009 hasConceptScore W2056226009C4839761 @default.
- W2056226009 hasConceptScore W2056226009C515602321 @default.
- W2056226009 hasConceptScore W2056226009C57805442 @default.
- W2056226009 hasConceptScore W2056226009C8010536 @default.
- W2056226009 hasIssue "6" @default.
- W2056226009 hasLocation W20562260091 @default.
- W2056226009 hasOpenAccess W2056226009 @default.
- W2056226009 hasPrimaryLocation W20562260091 @default.
- W2056226009 hasRelatedWork W1983253042 @default.
- W2056226009 hasRelatedWork W2056226009 @default.
- W2056226009 hasRelatedWork W2077304443 @default.
- W2056226009 hasRelatedWork W2081192963 @default.
- W2056226009 hasRelatedWork W2131523560 @default.
- W2056226009 hasRelatedWork W2194327752 @default.
- W2056226009 hasRelatedWork W2241832213 @default.
- W2056226009 hasRelatedWork W2925279542 @default.
- W2056226009 hasRelatedWork W2982066952 @default.
- W2056226009 hasRelatedWork W2093258893 @default.
- W2056226009 hasVolume "24" @default.
- W2056226009 isParatext "false" @default.
- W2056226009 isRetracted "false" @default.
- W2056226009 magId "2056226009" @default.
- W2056226009 workType "article" @default.