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- W2056904360 abstract "Erstmals wurden farblose, rhomboedrische Einkristalle von Ba[SnF6] („Kupferbömbchen”︁; 28 d; 750°C; Gemenge BaF2/met. Sn/CuF2 im Verhältnis Ba:Sn;Cu = 1:1:2) und Ba[TiF6] („Kupferbombe”︁; 35 d; 650°C; Gemenge BaF2/met. Ti/CuF2 im Verhältnis Ba:Ti:Cu=1:1:2) erhalten. Ba[SnF6] kristallisiert in der Raumgruppe R3 mit a = 742,79(9) pm und c = 741,8(2) pm, Vierkreisdiffraktometer Siemens AED 2, MoKα, R = 3,64% und Rw = 3,79% mit 344 aus 2047 gemessenen Io(hkl), Ba[TiF6] dagegen in R3m mit a = 736,76(9) pm und c = 725,2(1) pm, (Vierkreisdiffraktometer Siemens) AED 2, MoKα, R = 2,33% und Rw = 2,31% mit 202 aus 2004 gemessenen Io(hkl)) kristallisiert. Ba[SnF6] ist der erste Vertreter des K[OsF6]-Typs, dessen Struktur durch Einkristalldaten belegt wird. Die Struktur wird mit der von Ba[TiF6], einem Vertreter des Ba[SiF6]-Typs, verglichen. Der Madelunganteil der Gitterenergie, MAPLE, sowie „Mittlere Fiktive Ionenradien, MEFIR”︁, und „Effektive Koordinationszahlen, ECoN”︁, sowie die „Ladungsverteilungen”︁, „CHARDI”︁, werden berechnet und diskutiert. On the K[OsF6] Type: The Constitution of BaSnF6 and BaTiF6 Colourless single crystals of Ba[SnF6], a hitherto unknown representative of the K[OsF6] type as well Ba[TiF6] (Ba[SiF6] type) have been obtained. Ba[SnF6] (“Sealed copper) tube”; 28 d; 750°C; BaF2/met. Sn/CuF2 with Ba:Sn:Cu = 1:1:2) crystalizes in SPCG. R3 with a = 742.79(9) pm and c = 741.8(2) pm, (Four-circle diffractometer, Siemens AED 2, MoKα, R = 3.64% and Rw = 3.79%, 344 of 2047 Io(hkl). Ba[TiF6] (“Sealed copper tube”; 35 d; 650°C; BaF2/met. Ti/CuF2 with Ba:Ti:Cu = 1:1:2) crystalizes in the space group R3m with a = 736.76(9) pm and c = 725.2(1) pm, (Four-circle diffractometer, Siemens AED 2, MoKα, R = 2.33% and Rw = 2.31%, 202 of 2004 Io (hkl). BaSnF6 which is characterized by single crystal data is the first representative of the K[OsF6] type. Its structure is compared with that of Ba[TiF6], a fellow of the Ba[SiF6] type. The Madelung Part of Lattice Energy, MAPLE, “Mean Fictive Ionic Radii, MEFIR”, and “Effective Coordination Numbers, ECoN”, as well as the Charge Distribution, “CHARDI”, are calculated and discussed." @default.
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- W2056904360 date "1990-12-01" @default.
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- W2056904360 title "Zur Kenntnis des K[OsF6]-Typs: �ber die Konstitution von BaSnF6 und BaTiF6" @default.
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- W2056904360 doi "https://doi.org/10.1002/zaac.19905910102" @default.
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