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- W2058175020 abstract "The technique of external infrared reflection absorption spectroscopy combined with classical electrochemical techniques was used for the in situ characterization of the oxidation reactions of lead electrodes in sulfuric acid. The generation and consumption of lead sulphate on the lead electrode was measured during galvanostatic and potentiodynamic experiments. The amount of lead sulphate was quantitatively determined by integrating the area of a characteristic absorption band. Furthermore, the break down of the passive lead sulphate layer on the electrode connected with an oxidation of the lead electrode in the course of a cathodic cycle in a potentiodynamic experiment could be demonstrated." @default.
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- W2058175020 date "1993-03-01" @default.
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- W2058175020 title "In Situ IR external Reflection-absorption Spectroscopy as a Tool for Investigations of Electrodes in Aqueous Solutions: The Reactions of Lead Electrodes in Sulfuric Acid" @default.
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- W2058175020 doi "https://doi.org/10.1002/bbpc.19930970331" @default.
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