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• W2068211095 abstract "From a critical examination of the information which is obtainable on adsorption and nucleation of metallic layers using a simple field emission microscope, it is concluded that: (i) The field emitting specimen is unsuitable as a substrate for study of nucleation kinetics. (ii) The concentration of adsorbed metal on the tip apex may differ from that on the shank, but under the most probable conditions prevailing this difference will not exceed 50%. Thus Smith's view that thick layers are unstable at the tip apex is not supported by an analysis of stability based on equilibrium thermodynamics, (iii) Field emission microscopy can detect the location of points at which nucleation and growth of crystallites takes place, but cannot reliably reveal the shapes of crystallites. An examination of field emission micrographs reveals the presence of both stable and unstable crystallites on an adsorbate layer, and based on these considerations of stability a qualitative description is given of the processes of layer and crystallite growth which is consistent with the events observed in the field emission microscope." @default.
• W2068211095 created "2016-06-24" @default.
• W2068211095 creator A5058183769 @default.
• W2068211095 date "1974-02-01" @default.
• W2068211095 modified "2023-09-24" @default.
• W2068211095 title "Nucleation of metal crystals on field emitter substrates" @default.
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• W2068211095 doi "https://doi.org/10.1016/0039-6028(74)90058-2" @default.
• W2068211095 hasPublicationYear "1974" @default.
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