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- W2068362545 abstract "The molecular structure of one diastereomer of the dlnucleoslde methylphosphonate Tp{Me)sT (1) has been determined by X-ray diffraction methods. The crystal asymmetric unit contains one molecule of 1 and one methanol In an orthorhombic unit cell of dimensions a = 13.241(4), b = 13.844(3), c = 14.944(7) A, space group P212121. Both pyrimidlne bases In 1 are oriented antl relative to the 2′-deoxyribose rings, and the sugar conformations are 2E and 23T In the 4-thlothymidlne and thymldine moieties, respectively. The deoxyribose-phosphonate backbone has an extended conformation with the bases completely unstacked and almost parallel. The absolute configuration at the phosphorus center In 1 is Sp." @default.
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- W2068362545 date "1993-01-01" @default.
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- W2068362545 title "Molecular and crystal structure of Sp-thymidin-3'-yl 4-thiothymidin-5'-yl methylphosphonate" @default.
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- W2068362545 doi "https://doi.org/10.1093/nar/21.17.3921" @default.
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