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- W2070151034 abstract "Auger electron spectroscopy (AES) has been used to study the surface composition and electronic structure of hot-pressed samples of boron carbide. The samples had bulk compositions of ${mathrm{B}}_{9}$C and ${mathrm{B}}_{4}$C. After removing oxygen and excess carbon contaminants from the surfaces of the samples by noble-ion sputtering the AES estimates of surface B/C ratios were close to those of the bulk for each sample. Using the Auger data as a probe of the valence band (VB) of the samples, the shapes of the B KVV and C KVV lines were not found to be dependent on the stoichiometry of the sample, indicating that the local chemical bonding, respectively, for B and for C does not change significantly in going from ${mathrm{B}}_{9}$C to ${mathrm{B}}_{4}$C. Comparisons of the Auger line shapes with site-specific projected VB density-of-states calculations for ${mathrm{B}}_{13}$${mathrm{C}}_{2}$ by Armstrong et al. [Acta Crystallogr. Sect. B 39, 324 (1983)] indicated at least a limited agreement between theory and experiment in terms of the total VB bandwidth. The shapes of the Auger lines indicate that both s and p VB electrons take part in the Auger decays." @default.
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- W2070151034 title "Auger-electron spectra from boron carbide" @default.
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- W2070151034 doi "https://doi.org/10.1103/physrevb.31.3667" @default.
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