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- W2071031034 abstract "Monovalent cation binding sites on nucleic acids in solution can be localized using the isotopically labeled ammonium ion (15NH4+) as a probe in high resolution NMR spectroscopy experiments. The application of this technique to a series of DNA duplexes reveals a preference for the binding of ammonium cations in the minor groove of A-tract sequences. These results are consistent with a recent report which indicates that some solvent electron densities previously identified as water molecules in DNA X-ray crystal structures are partially occupied by sodium ions. The sequence-specific nature of monovalent cation binding sites demonstrated here for A-tract DNA provides an explanation for the origin of sequence-directed bending." @default.
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- W2071031034 date "1999-02-01" @default.
- W2071031034 modified "2023-10-18" @default.
- W2071031034 title "Localization of ammonium ions in the minor groove of DNA duplexes in solution and the origin of DNA A-tract bending 1 1Edited by I. Tinoco" @default.
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- W2071031034 doi "https://doi.org/10.1006/jmbi.1998.2513" @default.
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