FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2071892892> ?p ?o ?g. }

• W2071892892 endingPage "554" @default.
• W2071892892 startingPage "547" @default.
• W2071892892 abstract "NMR and ionic conduction measurements have been performed for two liquid-state high-molecular-weight comb-branched polyethers, which are macromonomers of cross-linked random copolymers, with and without LiN(SO2CF3)2 (LiTFSI) doping. The macromonomers are derivatives of glycerol bonded to (ethylene oxide)-co-(propylene oxide) (m(EO−PO)) and (ethylene oxide)-co-(2-(2-methoxyethoxy)ethyl glycidyl ether) (m(EO−GE)) with molecular weights of about 8 000 and 10 000, respectively. The dynamics of the lithium ion, anion, and the macromonomers were characterized by 7Li, 19F, and 1H NMR spin−lattice relaxation time (T1) and self-diffusion coefficient (D) measurements. Because the temperature dependence of the 1H and 7Li NMR T1 exhibited minima, the reorientational correlation times were able to be calculated. Above 278 K, the segmental motions in the neat liquid-state macromonomers are faster than those in the cross-linked state, and they become almost the same at lower temperatures and are slowest in m(EO−PO). When doped with LiTFSI the segmental motions in the liquid electrolytes slowed to values similar to those in the cross-linked polymer. The translational diffusion coefficients were in the order (fastest to slowest) of anions > lithium ions > macromonomers. The diffusion of the ions correlated well with the macromonomer diffusion. The ionic conductivity of doped m(EO−PO) was higher than that of doped poly(EO−PO), and comparison of the measured ionic conductivity with estimates of the ionic conductivity calculated from Danion and DLi indicates high ion dissociation in the macromonomer electrolytes. The results are consistent with a picture of the lithium ions undergoing local motions near the polymer chains, whereas the anions diffuse through a slowly fluctuating three-dimensional porous polymer matrix." @default.
• W2071892892 created "2016-06-24" @default.
• W2071892892 creator A5006369547 @default.
• W2071892892 creator A5023529165 @default.
• W2071892892 creator A5042813782 @default.
• W2071892892 creator A5060131526 @default.
• W2071892892 creator A5081825244 @default.
• W2071892892 creator A5085970804 @default.
• W2071892892 date "2001-12-20" @default.
• W2071892892 modified "2023-09-26" @default.
• W2071892892 title "An NMR and Ionic Conductivity Study of Ion Dynamics in Liquid Poly(ethylene oxide)-Based Electrolytes Doped with LiN(SO₂CF₃)₂" @default.
• W2071892892 cites W1965335922 @default.
• W2071892892 cites W1974719530 @default.
• W2071892892 cites W1984541834 @default.
• W2071892892 cites W1985204514 @default.
• W2071892892 cites W1989190179 @default.
• W2071892892 cites W1990189931 @default.
• W2071892892 cites W1990264855 @default.
• W2071892892 cites W1990770376 @default.
• W2071892892 cites W1998131795 @default.
• W2071892892 cites W2019014489 @default.
• W2071892892 cites W2019231090 @default.
• W2071892892 cites W2023311553 @default.
• W2071892892 cites W2028329272 @default.
• W2071892892 cites W2042970433 @default.
• W2071892892 cites W2056636477 @default.
• W2071892892 cites W2060823898 @default.
• W2071892892 cites W2063101742 @default.
• W2071892892 cites W2068077529 @default.
• W2071892892 cites W2073319355 @default.
• W2071892892 cites W2082092983 @default.
• W2071892892 cites W2082783838 @default.
• W2071892892 cites W2084761689 @default.
• W2071892892 cites W2094642735 @default.
• W2071892892 cites W2128890984 @default.
• W2071892892 cites W2131904845 @default.
• W2071892892 cites W4238642012 @default.
• W2071892892 cites W4241182524 @default.
• W2071892892 cites W4253345956 @default.
• W2071892892 doi "https://doi.org/10.1021/jp013035+" @default.
• W2071892892 hasPublicationYear "2001" @default.
• W2071892892 type Work @default.
• W2071892892 sameAs 2071892892 @default.
• W2071892892 citedByCount "51" @default.
• W2071892892 countsByYear W20718928922012 @default.
• W2071892892 countsByYear W20718928922013 @default.
• W2071892892 countsByYear W20718928922014 @default.
• W2071892892 countsByYear W20718928922015 @default.
• W2071892892 countsByYear W20718928922016 @default.
• W2071892892 countsByYear W20718928922017 @default.
• W2071892892 countsByYear W20718928922018 @default.
• W2071892892 countsByYear W20718928922019 @default.
• W2071892892 countsByYear W20718928922020 @default.
• W2071892892 countsByYear W20718928922021 @default.
• W2071892892 countsByYear W20718928922022 @default.
• W2071892892 countsByYear W20718928922023 @default.
• W2071892892 crossrefType "journal-article" @default.
• W2071892892 hasAuthorship W2071892892A5006369547 @default.
• W2071892892 hasAuthorship W2071892892A5023529165 @default.
• W2071892892 hasAuthorship W2071892892A5042813782 @default.
• W2071892892 hasAuthorship W2071892892A5060131526 @default.
• W2071892892 hasAuthorship W2071892892A5081825244 @default.
• W2071892892 hasAuthorship W2071892892A5085970804 @default.
• W2071892892 hasConcept C121332964 @default.
• W2071892892 hasConcept C131540310 @default.
• W2071892892 hasConcept C138679309 @default.
• W2071892892 hasConcept C145148216 @default.
• W2071892892 hasConcept C145912823 @default.
• W2071892892 hasConcept C147597530 @default.
• W2071892892 hasConcept C147789679 @default.
• W2071892892 hasConcept C154881586 @default.
• W2071892892 hasConcept C15920480 @default.
• W2071892892 hasConcept C159467904 @default.
• W2071892892 hasConcept C159985019 @default.
• W2071892892 hasConcept C161790260 @default.
• W2071892892 hasConcept C17525397 @default.
• W2071892892 hasConcept C178790620 @default.
• W2071892892 hasConcept C179104552 @default.
• W2071892892 hasConcept C185592680 @default.
• W2071892892 hasConcept C188027245 @default.
• W2071892892 hasConcept C191897082 @default.
• W2071892892 hasConcept C192562407 @default.
• W2071892892 hasConcept C24890656 @default.
• W2071892892 hasConcept C2777801237 @default.
• W2071892892 hasConcept C2778597550 @default.
• W2071892892 hasConcept C2779851234 @default.
• W2071892892 hasConcept C2992561413 @default.
• W2071892892 hasConcept C49040817 @default.
• W2071892892 hasConcept C521977710 @default.
• W2071892892 hasConcept C57863236 @default.
• W2071892892 hasConcept C59593255 @default.
• W2071892892 hasConcept C68801617 @default.
• W2071892892 hasConceptScore W2071892892C121332964 @default.
• W2071892892 hasConceptScore W2071892892C131540310 @default.
• W2071892892 hasConceptScore W2071892892C138679309 @default.
• W2071892892 hasConceptScore W2071892892C145148216 @default.
• W2071892892 hasConceptScore W2071892892C145912823 @default.
• W2071892892 hasConceptScore W2071892892C147597530 @default.

• next